固体物理作业题固体理作业题.docVIP

Chapter 1 Problem 1.1: Compute the packing fraction f for the bcc lattice. Problem 1.2: (a) Show that the packing fraction f for the diamond lattice is π 3 /16 . (b) What is the packing fraction and coorination number of the honeycomb lattice? Problem 1.3: Consider the hexagonal close packed lattice. (a) Show that c = a 8 3 = 1.633a . Frequently a crystal structure is called hcp even c is not exactly equal to the ideal value. (b) Show that the packing fraction for the ideal hcp lattice is π 2 / 6 = 0.7405 Problem 1.4: The ionic compound A+B- crystallizes in the NaCl structure. Plot the packing fraction as a function of the ratio + ? ζ = r / r . Assume that ζ 1. Problem 1.5: Repeat the calculation of problem 1.4 for the CsCl structure. Problem 1.6: Use the information in the textbook to calculate the densities (in kgm-3) of the following solids: (a) Aluminum, (b) Iron, (c) Silicon and (d) Zinc. Atomic weights of some common elements are listed in the textbook. Problem 1.7: SrTiO3 crystallizes in the perovskite structure. The strontium atoms are at the corners of the cube with side a, the titanium atoms are at the body center, while the oxygen atoms occupy the cube faces. (a) What is the Bravais lattice type? 2 (b) Verify that the primitive unit cell contains one Sr, one Ti and three O atoms. (c) Write down a set of primitive lattice vectors and basis vectors for the perovskite structure. Problem 1.8: The primitive lattice vectors of a certain Bravais lattice can be written R n n ax n by n zv r r r 1 2 2 1 3 ( 2 ) 1 2 = 1 + + + What is the lattice type? Problem 1.9: In each of the following cases indicate whether the structure is a Bravais lattice. If it is, give three primitive lattice vectors. If it is not describe it as a Bravais lattice with as small as possible basis. In all cases the length of the side of the unit cube is a. (a) Base centered cubic (simple cubic with additional points in the centers of the horizontal faces of the cubic cell). (b)