硼钨杂多酸对半菁染料敏化剂光电性能的影响[精选].doc

硼钨杂多酸对半菁染料敏化剂 光电性能的影响 摘 要 关键词：多金属氧酸盐；半菁染料；静电自组装； Abstract In this paper, ten inorganic-organic hybrid composite films based on the series of BW polyoxometalates, and mixed hemicyanine dyes were fabricated by using electrostatic self-assembly technology. The assembly process and film-forming properties were characterized by using UV-vis spectra, and the results showed that composite films were assembled orderly, level uniformed and stable. The inorganic components in the most of films are able to interact with hemicyanine to get the absorption red-shifted so as to extend the absorption active range of sunlight.When irradiated with white light, the inorganic-organic hybrid composite films gave a stable cathodic photocurrent.The research shows that the generation of the cathodic photocurrent due to the transition of the charge in the Hemicyanine, but the size of the photocurrent is affected by the POMs. In addition, The effects of the applied bias voltages, layer numbers of the films , light intensities, pH value were examined. Key words: polyoxometalate, hemicyanine dye, electrostatic self-assembly, photoelectrochemical properties 目 录 1.1 引言 1 1.2太阳能电池 1 1.2.1太阳能电池的 1 1.2.2 染料敏化太阳能电池 2 1.2.2染料敏化太阳能电池 2 1.2.2.2染料敏化太阳能电池 3 1.3 多金属氧酸盐 7 1.3.1 多金属氧酸盐 7 1.3. 7 1.4 本课题的选择及目的 10 2.1 硼钨系列杂多酸/C1半菁自组装膜的制备与表征 12 2.1.1 实验试剂与仪器 12 2.1.2自组装膜的制备 12 2.1.3 自组装膜的表征 13 2.自组装膜的 16 2.2.1 实验仪器与试剂 16 2.2.2 工作电极的制备 16 2..3 BWX系列单层膜电极 17 2.2.4 BWX/C1系列膜电极的电化学行为 21 2.3 硼钨系列杂多酸/C1自组装膜的光电性质 23 2..1 实验仪器与试剂 23 2..2 工作电极的制备 23 2..3 光电测试系统 24 2.3.膜的光电响应行为 24 .4 小结 32 3.1 BWV杂多酸/C3自组装膜的制备与表征 32 .1.1 实验试剂与仪器 32 .1.2 BWV杂多酸/C3系列自组装膜的制备 32 .1.3 BWV杂多酸/C3系列自组装膜的表征 32 .2 BWV杂多酸/C3自组装膜的 35 3.2.1 实验仪器与试剂 35 .2.2 工作电极的制备 35 35 3.3 BWV系列杂多酸/C3自组装膜的光电性质 37 .3.1 实验仪器与试剂 37 .3.2 工作电极的制备 37 .3.3 BWV系列杂多酸/C3自组装膜的光电响应行为 38 .4 小结 44 4.1 BW11V/C6自组装膜的制备与表征 44 .1.1 实验试剂与仪器 44 .1.2 BW11V/C6系列自组装膜的制备 44 .1.3 BW11V/C6自组装膜的表征 44 .2 BW11V/C6自组装膜的 45 4.2.1 实验仪器与试剂 45 .2.