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Journal of Himalayan Earth Sciences 45(1) (2012) 31-52 Mineralogy and geochemistry of diorites and associated hydrothermal sulfide mineralization of Gawuch Formation in Drosh area, Chitral, northern Pakistan Tazeem Tahirkheli, M. Tahir Shah, M. Asif Khan and Rubina Bilqees National Centre of Excellence in Geology, University of Peshawar, Pakistan Abstract Sulfide mineralization in Drosh-Shishi area is related to hydrothermal activity which is mainly associated with altered diorite and quartz veins of Gawuch Formation. This Formation comprises variably metamorphosed volcanics and sediments intruded by plutons of diorite and granodiorite composition. Three varieties of diorites are distinguished in the studied area. These include 1) diorites, 2) altered diorites and 3) gneissose diorites. All types of diorites are mineralogically similar having major constituent minerals like plagioclase, orthoclase, amphibole and quartz. Calcite, chlorite, and epidote occur as minor secondary minerals while muscovite, biotite and ore occur as accessory phases. Detailed geochemistry, mainly based on major and trace elements, suggests that the magmatism responsible for Gawuch Formation was calc-alkaline and contains strong subduction component. Sulfide mineralization occurs in association with diorites and quartz veins, along foliation planes, as dissemination and as supergene enrichment. Tetrahedrite, chalcopyrite, pyrite and galena are dominant ore minerals with subordinate amounts of sphalerite, magnetite, malachite and azurite. Electron microprobe analyses show the pure nature of these ore phases. A variable gain and loss of MnO, K2O, Na2O and P2O5 are noticed in mineralized diorite which shows an enrichment of Cr, Zn, Mo, Cd, Ag and Au. Both mineralized diorites and mineralized quartz veins have a high δ18O signature, suggesting the involvement of isotopically heavy ore forming fluid in the alteration and copper mineralization. Keywords: Petrochemistry; Sulfide-mineral