(结构化学.pptVIP

第三章 双原子分子结构例题与练习 * * Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 例1．变分法的应用：利用变分函数 ψ=x(x-l)，求一维势箱(边长为l)中运动粒子基态能量的近似值。 解：根据变分法原理： 与一维势箱解法相比 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 例2．证明 的两个分子轨道正交 Evaluation only