KH570改性阴离子PAM驱油剂的合成与性能研究.docxVIP

KH570改性阴离子PAM驱油剂的合成与性能研究摘 要我国大部分大型油田如：大庆油田、胜利油田都进入了二次采油的末期，产量都有不同程度的递减，而新增储量的增加越来越缓慢，并且勘探成本和难度也越来越大，因此控制含水率，稳定目前原油产量，在最大程度的提高最终采收率，经济合理的予以利用和开发，对整个石油工业有着举足轻重的作用。聚合物驱机理就是在注入水中加入高分子聚合物，增加驱替相粘度，调整吸水剖面，增大驱替相波及体积，从而提高最终采收率这一要求的技术。实验结果显示：在70℃下，反应配比AM(丙烯酰胺)：KH570:AA(丙烯酸)=7:0.4:2，固配比为4%的情况下，以过硫酸钾为引发剂，其质量为单体总质量的0.5%，将其PH值控制在7-8之间合成聚丙烯酰胺，得到的大分子聚丙烯酰胺。其分子量较其他体系的分子量大，表面张力小，驱替效率较大，驱油效率最高。取最好的聚丙烯酰胺测其不同浓度下的表面张力，测的在0.55g/L时，其表面张力最小。关键词：聚丙烯酰胺，丙烯酸，阴离子型，驱油剂，聚合物驱，波及效率The Synthesis of Modification Anionic KH570 PAM Flooding Oil Polymer and Performance ResearchABSTRACTMost large oil fields in China，such as DaQing oilfield, ShengLi oilfield ,have entered the end of the secondary oil recovery， production has had different degree of decline, but the new reserves has increased more and more slowly, and the exploration cost and difficulty have bigger and bigger. So controlling water cut, the stability of the output of crude oil, the maximum improve ultimate recovery, economic and reasonable use and development, have a pivotal role on the entire oil industry. Experimental results showed that under 70℃,the ratio of reaction of AM (acrylamide) : KH570: AA (acrylic acid) = 7:0. 4:2, ratio of solid to 4% of cases, with potassium persulfate as initiator, the 0.5% of the total quality of quality as the monomer, the PH value control between 7 and 8 synthetic polyacrylamide, macromolecular polyacrylamide. Its molecular weight than other systems of large molecular weight, the surface tension of small, displacement efficiency is bigger, its highest flooding efficiency.Take the best polyacrylamide measuring the different concentrations of surface tension, measured at 0.55 g/L, the surface tension is minimal KEY WORDS: Polyacrylamide, acrylic, anionic, oil displacement agent, polymer flooding , the sweep efficiency 目 录摘要IABSTRACTII1 文献综述31．1前言31.1 .1 现阶段我国油田现状31.2聚合物驱油剂概述31.2.1 聚合物驱油机理31.2.2 聚合物类型31.3聚丙烯酰胺的物理性质31.3.1基本性质31.3.2流动性质31.3.3 稳定性31.3.4 絮凝作用31.3.5 降低粘滞拽力31.4 聚丙烯酰胺的化学性质31.4.1 水解反应31.4.3 磺甲基化反应31.