树叶状Co和Co3O4的水热合成与磁性研究.doc

树叶状Co和Co3O4的水热合成与磁性研究 吴明在1,2，赵修彬1，庞占文1，王培养1，方明亮1，戴鹏1，刘先松2 （1.安徽大学 教育部光电信息获取与控制重点实验室，安徽合肥 230039； 2.安徽大学 安徽省磁性材料工程技术研究中心， 安徽合肥 230039） 摘 要: 采用水热工艺，还原氯化钴（CoCl2?6H2O）制得微米级的树叶状钴单质，并在500oC退火的条件下得到形貌相似的Co3O4。采用X射线衍射（XRD）、扫描电子显微镜（SEM）、振动样品磁强计（VSM），对所得粒子的结构、形貌和磁性能进行了初步研究。结果表明，树叶状钴单质表现出室温铁磁行为，具有较高的磁参数，饱和磁化强度和矫顽力分别为139.3emu/g、370Oe。同时500℃退火1小时后的Co3O4也表现出极弱的铁磁性行为，可能是由于未完全氧化的Co单质所产生。 关键词:水热;微观结构；树叶状；磁性能 Synthesis and Magnetic property of Co and Co3O4 with leaf-like morphology WU Mingzai1,2, ZHAO Xiubin1 PANG Zhanwen1, WANG Peiyang1, FANG Mingliang1, DAI Peng1, LIU Xiansong2 （1. Key Laboratory of Opto-electronic Information Acquisition and Manipulation (Anhui University), Ministry of Education, Hefei 230039, People’s Republic of China. 2.Engineering Technology Research Center of Magnetic Materials (Anhui University)，Anhui Province，Hefei 230039, People’s Republic of China） Abstract: Leaf-like Co microcrystals have been prepared via a hydrothermal reduction reaction using CoCl2?6H2O as starting materials. After being annealed at 500 oC for 1h, Leaf-like Co microcrystals were transformed to Co3O4 with the morphology kept unchangeable. X-ray diffractometer (XRD), transmission electron microscope (TEM),and vibrating sample magnetometry (VSM) measurements were carried out to investigate their structures，morphologies and magnetic properties. Based on the measurement results, it was found that the fractal leaf-like Co exhibited ferromagnetic behavior with a saturation magnetization of 139.3emu/g and a coercivity of 370 Oe at room temperature. While Co3O4, exhibited a weak ferromagnetic characteristic, which was possibly due to the unreacted metal Co. Key words: hydrothermal process; microstructure; dendrite-like; magnetic peoperties 1引言 由于金属钴粒子在磁流体、先进材料、催化和高密度磁存储等领域有广泛的潜在应用价值，备受科研人员的青睐[1-4]。随着研究的深入，各种结构的钴粒子被成功的制备出来，包括线状结构、片状结构、环状结构、链状结构等[1-4]。例如。Pan等人[2]在硅片的表面，采用模版辅助的办法，成功制备了片状的Co纳米粒子；Zhang等人[4]选用酒石酸钠作配位计、SDS作表面活性，采用水热的办法，合成了由微米球自组装成的链状钴单质。尽管科研人员在制备单质钴领域的研究已取得了一定的进展，但是采用水热的办法来合成树叶状钴