现代光分析化学试考题.docVIP

现代光分析化学考试题 专业：分析化学（分科所） 学号：200820948 姓名：王小梅 题目：以你所掌握的知识，说明光化学分析的发展趋势及其在有机、无机、生物、药物食品环境等领域的应用，并举例（1～２例）说明其当前的研究热点。（by English 3000 words） Spectroscopy covers a very wide area which has been widened further since the mid-1960s by the development of lasers and such techniques as photoelectron spectroscopy and other closely related spectroscopies. It occupies a very special position in chemistry, physics and in science ingeneral. It is capable of providing accurate answers to some of the most searching questions, particularly those concerning atomic and molecular structure. For small molecules, it can provide accurate values of bond lengths and bond angles. For larger molecules, details ofconformation can be obtained. Is a molecule planar? If it is non-planar, what is the energy barrier to planarity? Does a methyl group attached to a benzene ring take up the eclipsed or staggered position? Is a cis- or trans- conformation more stable? It also provides techniques that are vital in chemical analysis. What we can call it Analytical spectroscopic chemistry. Analytical spectroscopic chemistry is basically an experimental subject and is concerned with the absorption, emission or scattering of electromagnetic radiation by atoms or molecules. It contains Raman Spectroscopy, Fluorometry Phosphorimetry, Chemiluminescence, Flame Emission, Atomic Absorption, Atomic Fluorescence Spectrometry, Emission Spectroscopy, Radiochemical Methods of Analysis, Structural Analysis, and Microwave Spectroscopy. Among this, Emission spectroscopy is con?ned largely to the visible and ultraviolet regions, where spectra may be produced in an arc or discharge or by laser excitation. Absorption spectroscopy is, generally speaking, a more frequently used technique in all regions of the spectrum and it is for this reason that we shall concentrate rather more on absorption. Sometimes, we can divide the Spectroscopy into Rotational spectroscopy, Vibrational spectroscopy, Electronic spectroscopy, Pho