无机固体电解质材料的基础与应用研究_培训课件.pdfVIP

41 2015 1 Energy Storage Science and Technology Vol.4 No.1 Jan. 2015 315201 NASICON 3 3 NASICON doi: 10.3969/j.issn.2095-4239.2015.01.001 TM 911 A 2095-4239 2015 01-001-18 Research progress of inorganic solid electrolytes in foundmental and application field HUANG Zhen YANG Jing CHEN Xiaotian TAO Yicheng LIU Deng GAO Chao LONG Peng XU Xiaoxiong Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences Ningbo 315201 Zhejiang China Abstract Due to high safety, long service life and high energy density, all-solid-state lithium battery has a good application prospect in high-safety chemical power source field. As the key part of all-solid-state lithium battery, solid electrolytes have attracted lots of attention and have been thoroughly studied for many years, but only few solid electrolytes showed good performance. NASICON-type oxide electrolytes, garnet-type oxide electrolytes and sulfide electrolytes possess high conductivities at room temperature, thus have been regarded as solid electrolytes with great application potential. This article presents?a brief review of the researches on these solid electrolytes?from the aspects of structural characteristics, preparation and modifications.?The challenges and prospects of?the applications?of solid electrolytes in all-solid-state lithium battery?are also stated. Key words NASICON-type garnet-type sulfide solid electrolyte all-solid-state lithium battery 1 ???????????????????????????????????????? ???????????????????? ? 2014-10-04 ? 863 2013AA050906 XD? 1985 NASICON huangzhen@nimte.ac.cn E-mail E-mail xuxx@nimte.ac.cn [1] 2 [2] 0.5 eV [3] –70~500 [2, 5-7] LISICON 2015 S2? O2? Li2S-P2S5 Li2S-P2S5-MeS2 Me=Si Ge Sn 4 NASICON —— 1 NASICON [4] NASICON O2? NASICON sodium super ion conductors [8] 1976 1968 Goodenough Hong[9] Na3Zr2Si2PO12 NASICON Na+ M[A2B3O12] MAB BO4 R3c AO6 [10] AO6 6 BO4 BO4 4 AO6 M+ MI MII MI→MII MII→MII M+ NASICON c 1 MII MI MI M+ MII NASICON M+ MIMII MIIMII M+ [A2B3O12]?