吸附生物再生法处理含汕废水的研究.pdf

??-????????????∈??お TREATMENT OF OILY WASTEWATER BY ADSORPTION-BIOLOGICAL REGENERATION ABSTRACT In “11-5” program, we bring forward the logo -----“saving energy and reduce abandon”. The most common method was adsorption which speed was very fast, but the regeneration was very difficult. Discarding or burning adsorbent usually bring the second pollution to the environment. Thereby, we put forward a new craft that combined adsorption and bio-treatment which called adsorption-biological regeneration. The key technology of the craft that adsorption-biological regeneration was to select an effective adsorbents and search for the optimumz condition for biological regeneration. Through comparing some absorbents just as fly ash, expanded graphite, EG-power composite and petrol coke.Finaly, we have chosen fly ash as our absorbents in this experiment. Fly ash as a solid wastes used in the depth of oily wastewater treatment economic and effective. Dipping FA which particle size was 20 mesh with 0.2 mol/L HCl after 16 h, the intercept hole in FA was opened and formed some new macroporous. The particle size of FA was increased from 4.98 nm to 11.32 nm., the specific surface area of FA was declined from 11.29 m2/g to 2.09 m2/g. Using the modified FA to treat oily wastewater, The adsorption properties were evaluated by determination of the oil removal rate through static adsorption and dynamic adsorption. We discussed the effect of the dosage of FA, temperature, the initial pH and salinity of wastewater, on adsorption of FA. The result indicated, the optimum operating conditions to static adsorption were the following: particle size of FA was 20 mesh, addition amount FA was 33 g/L, the temperature was 30 ?, the initial pH was 10. The final oil removal rate was 90%. The optimum operating conditions to dynamic adsorption were the following: Temperature was 30 ?, the initial pH was 10the velocity of flow was 8 BV/h, the average of the concentration in wastewater was 9.639 mg/L, the t