Natural gas makes life better 天津大学研究生e 天然气让生活更天津大学研究生E.pptVIP

The synthesis of MoS2 nanotubes The procedure for the growth of porous sheets of aluminum oxide aluminum plates 40v HOOC-COOH Al+3 OH- H+ e Al+3 H2 e + Al2O3 10 hours gradually reduce the voltage 25 ％ H2SO4 e e The synthesis of MoS2 nanotubes soak the electrode for several hours Al2O3 detaches from the electrode Rinse several times with deionized water templates 70℃ Al2O3 template (NH4)2MoS4 DMF solution 10 ％ H2 90 ％ N2 20ml/min 10 ℃/min 450 ℃ Constant T for 1 h Solution of NaOH 30min Rinse with distilled water The synthesis of MoS2 nanotubes +2NH3 (NH4)2MoS4+H2 +2H2S N2 450℃ MoS2 The synthesis of MoS2 nanotubes the size and shape of the MoS2 tubules and fibers could be controlled diameters ranging from 50 to 330 nm lengths approaching 30-60 μm The synthesis of MoS2 nanotubes Figure 1. An SEM micrograph of the MoS2 fibers after dissolution of the Al2O3 template. Figure 2. A TEM image of the MoS2 tubules after dissolution of the Al2O3 template Figure 3. A TEM image of a bend in a tubule of MoS2 emphasizing the hollow nature of the tubules The synthesis of MoS2 nanotubes MoO3+H2S MoS2 95％N2,5％H2 800℃ Rao’ group a MoS3 intermediate decompose MoS2 nanotubes The synthesis of MoS2 nanotubes (NH4)2MoS4 MoS3 + H2S + NH3 T=400 ℃ in an Ar atmosphere an excellent yield of nanotubes The outer diameter :30 -45 nm and the inner diameter : 7-8 nm MoS3 + H2 MoS2 + H2S T=1200 ℃-1300 ℃ 30 50 120 The synthesis of MoS2 nanotubes TEM images of MoS2 nanotubes obtained by the treatment of MoS3 with hydrogen at 1300 ℃ The synthesis of MoS2 nanotubes MoS3 itself is a decomposition product of (NH4)2MoS4 directly heat (NH4)2MoS4 in a hydrogen atmosphere +2NH3 (NH4)2MoS4+H2 +2H2S 1200-1300℃ MoS2 The outer diameter :25nm The synthesis of MoS2 nanotubes 120 Reaction Heat treatment :700 ℃ -800 ℃ 1 hour Inlet constant Ar flow (200ml/min) Heat materials:Mo(CO)6 150℃ , S 250℃ Flush with Ar for an hour deposition anneal 450℃ Amorphou