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Prehistoric Metallurgy El Camino College史前冶金埃尔卡米诺学院
Metals sporadically occur in nature in pure enough concentrations that they were recognized and exploited in prehistoric times. Softer metals like gold and copper can be worked by hammering without heating. It is surmised that ceramic production created the technological foundation for the smelting of metal. Copper ores come in two basic forms: sulphides and oxides. Sulphide ores contain a metal combined with sulphur. Early miners were attracted to oxides because they were easily recognizable, accessible, and easier to prepare for smelting. Sulphide ores have to be roasted before they are smelted. Early miners were limited to metal deposits occurring on the surface. Once extracted, it was necessary to pound the ore to separate the metal ore from the gangue – the worthless host rock. The melting point of copper is 1100? Celsius. The earliest smelting used charcoal and blow pipes. The copper would be melted in the furnace and collected after cooling in the form of prills, or round droplets. These would then be melted in a crucible. Molten copper would be poured into an open mold of stone. The earliest copper artifacts in the Middle East were trinkets such as bracelets and beads. In northern Europe tools such as axes and awls were made. These quickly replaced their stone and bone counterparts. As metal demand increased, and higher grade ores became exhausted, smelters turned to slagging processes to increase production and efficiency. Fluxes like sand and manganese were added to enhance the separation of the silica rich slag from the metal. It was discovered that adding arsenic or tin to copper produced a metal that was harder. The resulting metal is bronze. Tin is a rarer metal than copper, and trade routes came into being to transport tin over long distances. More complex tools and weapons were made during the Late Bronze Age, enabled by clay molds and the lost wax technique. Iron Age Vietnamese bronze drum made by the lost wax technique. X-ray flores
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