以水为溶剂的明胶电纺丝纳米纤维的制备研究.pdfVIP

762 50w/v% GTA 1 SEM 763 3.1 22kV 25 0.3mL/h 42 54mg/mL 10cm [18] 10cm 1 22kv 40 54 w/v% 1 2 1 40 764 0.3ml/h Counts 20 18 16 14 12 10 8 6 4 2 0 40 80 120 160 Diameters(nm) (a) 30 25 20 15 10 5 0 120 140 160 180 200 Diameters(nm) Counts Counts Counts 25 20 15 10 5 0 40 80 120 160 200 Diameters(nm) (b) 25 20 15 10 5 0 50 100 150 200 250 300 Diameters(nm) (c) (d) 1. SEM ( : 42w/v%(a), 46w/v%(b), 50 w/v%(c) and 54 w/v%(d), 40±1 ) Fig.1. SEM photograph of electrospun gelatin fibrous mat (concentration:42w/v%(a), 46w/v%(b), 50 w/v%(c) and 54 w/v%(d); temperature: 40 ) 765 1. SEM Table.1. The fiber diameter distribution analysis of the SEM of the gelatin nanofiber electrospun from solution of different concentration SEM a b c d (nm) 111.37 117.32 158.21 145.52 (nm) 40 190 40 220 120 210 50 300 90 140 100 140 140 170 100 170 (nm) 3.2 2.343% 22 - 1.534MPa 6.278MPa 1.022% 2. Table.2. Tensile properties of electrospun gelatin fibers before and after crosslinking Tensile stress(MPa) Strain at break(%) 1.53 2 6.278 MPa MPa 1.6 1.2 0.8 0.4 0.0 0.0 0.5 1.0 1.5 2.0 2.5 8 6 4 2 0 0.0 0.4 0.8 1.2 a (b) 2. a b Fig.2. Tensile stress-strain curve of electrospun gelatin fibers before(a) and after(b) crosslinking 766 50w/v% [1] Zheng-Ming Huang, Y.-Z. Zhang, M. Kotaki,et.al. A review on polymer nanofibers by electrospinning and their applications in nanocomposites. Composites Science and Technology[J]. 2003,63:2223–2253 [2] Satoru Kidoaki, Il Kuen Kwon, Takehisa Matsuda. Mesoscopic spatial designs of nano- and microfiber meshes for tissue-engineering matrix and scaffold based on newly devised multilayering and mixing electrospinning techniques[J]. Biomaterials. 2005,26:37–46 [3] Seeram Ramakrishna1, Kazutoshi Fujihara,Wee-Eong Teo. Electrospun nanofibers: solving global issues[J]. Materialstoday,2006,9(3):40-50 [4] Audrey Frenot, IoannisS. Chronakis. Polymer nanofibers assembled by electrospinning[J]. Current Opinion in Colloid and Interface Science.2003,8:64–75 [5] Dan Li, Yuliang Wang,