以离子液体为模板剂合成纳米超微孔ZrSiO2.pdfVIP

以离子液体为模板剂合成纳米超微孔Zr-SiO2 贾爱忠，李洁，刘双喜* （南开大学化学学院新催化材料科学研究所，天津 300071；中国） 摘要：超微孔分子筛在工业应用和科学研究中有重要的潜在意义，已倍受众多科学家关注。传统沸石分子筛 孔径较小，对于诸如精细化学品、中间体分子和大的有机分子不具备择形催化性能, 从而影响其在重油炼制、 制药等方面的应用。本文以咪唑类离子液体为模板剂在较温和的环境下合成纳米超微孔含锆二氧化硅多孔材 料，分别考察了碱源、晶化温度、晶化时间以及氧氯化锆组分等合成条件的影响。通过扫描电镜、X 射线衍 射、红外光谱以及氮气吸附脱附研究发现：反应体系中加入氧氯化锆能明显减小样品粒度，锆能有效地进入 到多孔材料的骨架中，去除模板剂后多孔材料能够保持骨架结构没有坍塌,X射线衍射峰强度明显提高。本合 成方法简单方便，具有很好的工业化前景。 关键词：离子液体，超微孔，纳米，Zr-SiO2 ，多孔材料 Synthesis of Nanometer Super-microporous Zr-SiO via Ionic 2 Liquid Templating JIA Ai-zhong, LI Jie, LIU Shuang-xi (Institute of New Catalytic Materials Science, College of Chemistry, Nankai University, Tianjin 300071, China) Abstract: The important potential value of the super-microporous material in the industrial application and academic value has been focused by many researchers in recently years. The pore diameter of conventional molecular sieve is smaller than the molecular of fine chemicals, medicine intermediate and other organic large moleculars, so the conventional molecular has no shape selectively of catalysis and its using in the heavy oil refine process and drug et al. is limited seriously. In this paper the nanometer super-microporous Zr-SiO2 molecular sieve with pore diameter 1.739nm and surface 2 area 848.82 m /g was prepared via imidazolium-based ionic liquids templating at mild conditions. The effects of alkali source, crystallization temperature, crystallization time and the addition agent of zirconyl chloride were discussed respectively. The synthesized samples were characterized by the scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier t