Short-circuit current improvement in CdTe solar cells by combining a ZnO buffer layer and a solution back contact.pdfVIP

Short-circuit current improvement in CdTe solar cells by combining a ZnO buffer layer and a solution back contact.pdf

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Short-circuit current improvement in CdTe solar cells by combining a ZnO buffer layer and a solution back contact.pdf

Current Applied Physics 17 (2017) 47e54 Contents lists available at ScienceDirect Current Applied Physics journal homepage: /locate/cap Short-circuit current improvement in CdTe solar cells by combining a ZnO buffer layer and a solution back contact Eun Seok Cha, Young Min Ko, Seon Cheol Kim, Byung Tae Ahn* Dept. of Materials Science and Engineering, Korea Advanced Institute of Science and Technology, 291 Daehak-ro, Yuseong-gu, Daejeon, 34141, Republic of Korea article info Article history: Received 18 August 2016 Received in revised form 18 October 2016 Accepted 20 October 2016 Available online 22 October 2016 Keywords: CdTe solar cells ZnO buffer layer Cu solution contact Short circuit current Quantum ef?ciency abstract Conventional CdTe solar cells have a CdS window layer, in which an absorption loss of photons with more than 2.4 eV occurs through the CdS layer. A thinner CdS layer was applied to enhance light transmission and a ZnO buffer layer with a band gap of 3.3 eV was introduced to suppress shunting through the thinner CdS window layer. A 100-nm thick ZnO layer sputter-deposited at 300 C had uniform coverage on a transparent conductive oxide (TCO) after a subsequent high-temperature process. The ZnO layer was effective in preventing shunting through the CdS window layer so that the open-circuit voltage and ?ll factor of the CdTe solar cells were recovered and the short-circuit current was enhanced over that of the conventional CdTe solar cell. In the ZnO/CdS/CdTe con?guration, the short-circuit current was further improved throughout the visible wavelength region by replacing the Cu-metal contact with a Cu solution contact. As a result the short-circuit current from 21.7 to 26.1 mA/cm2 and the conversion ef?ciency of the CdTe solar cell increased from 12 to 15% without antire?ective coating. Our result indicates that the Cu solution back contact is a critical factor for achieving a higher cell ef?ciency in addition to ZnO buffer layer. ? 2016 Elsevier B.V

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