结晶理论PLACAB.pptxVIP

Outline Background Experimental Section Results and Discussion Conclusion Tip 1: (2) 通过中间相、小晶块形成片晶的高分子结晶新模型: 高分子结晶不是直接从熔体到片晶的过程，而是借助于中间相和小晶块； 晶体的形成不需要成核，从一维有序的中间相到三维有序晶体是通过协同作用进行的 Tip 2: tinterm : 形成intermediate structure 的起始时间； tcry,noHB : 形成 crystals without HBs 的起始时间； tcry,HB : 形成 crystal with HBs 的起始时间； t1: 诱导期，与tcry,noHBs 对应； t2: 二次结晶起始的时间，与tcry,HBs 对应 Why they do the job? Researches on PHB/CAB blends (1) Blends of PHB/CAB have been proved to improve the mechanical toughness of PHB. (2) Crystallization kinetics of PHB/CAB blend influences their crystalline superstructures and degree of crystallinity developed under given processing conditions, and hence their physical properties. El-Shafee et al. indicated that PHB/CAB blends in melt states are miscible and the spherulites growth rates of PHB are remarkably reduced in the blends. Park et al. reported that the orientation behavior of PHB crystals upon drawing of the blends depends on the blend composition; c-axis orientation will be changed to a-axis orientation with increasing the CAB content in the blends. (3) We found that there are inter HBs between PHB and CAB; intra HBs within CAB and weak intra HBs within PHB. The intra HBs of stabilize the chain folding in the lamellar structure of PHB. The physical cross-links formed in PHB and CAB chains in the blends due to inter have been proposed to reduce mutual diffusivities of the chains and hence to reduce the crystallization rate and crystallinity of PHB under given crystallization conditions. Therefore, it is very interesting to investigate these HBs during the crystallization process of PHB in PHB/CAB blends and there are no report exploring the effects of inter and intra HBs on crystallization kinetics and mechanism of PHB/ CAB blends. What they get from the job? Experimental section Materials NOH (HCAB) NOH (LCAB) Ds (HCAB) Ds(LCAB) Mn(HCAB) Mn(LCAB) Sample Preparation Time-Resolved FTIR Measurements 32 s