磁性膨润土净水剂制备及其应用.pdfVIP

磁性膨润土净水剂制备及其应用 曹吉林 陈学青 刘秀伍 谭朝阳 安立君 张魁 （河北工业大学化工学院，天津，300130） 摘要：针对粉末状膨润土在水处理应用中存在固液难以分离的问题,进行了磁性膨润土新型吸附剂开发的研究. 通过膨润土提纯、在二价和三价铁离子混合溶液中用氨水调节负载铁的氧化物及真空干燥等步骤，制备了一 系列磁化率不同的磁性膨润土产品。对产品进行XRD、SEM及磁化率表征分析可知，膨润土表面负载的是四氧 化三铁，其磁化率的大小随所负载铁含量的增加而增大。对水中微量氯乙酸和铅离子的吸附考察得知，磁性 膨润土产品的吸附性能与原粉末状膨润土相当，但是对铅离子的吸附性能要比活性炭高好多。本文制得的磁 性膨润土产品可以用磁分离技术技术非常容易地从溶液中分离出来，而且制备工艺简单，反应条件温和，在 实际生产中具有广阔的应用前景。 关键词： 膨润土； 磁性； 净水剂； 吸附； 氯乙酸 Preparation and Application of Magnetic Bentonite Clean Water Reagent CAO Ji-lin CHEN Xue-qin LIU Xiu-wu TAN Zhao-yang AN Li-jun ZHANG Kui (School of Chemical Engineering, Hehei University of Technology , Tianjin , 300130, China ) Abstract: In view of the difficult separation problem of powder bentonite from solution in water treatment, the development of new type magnetic Bentonite adsorbent was studied in this article. A series of magnetic Bentonite products with different magnetic susceptibility were prepared through Bentonite purification, loading iron oxide in mixture solution of Fe2+ and Fe3+ by ammonia adjusting and drying in vacuum condition. The XRD, SEM and magnetic susceptibility of Characterizing the products showed that Fe O is loaded in Bentonite surface and the magnetic susceptibility is 3 4 increasing with the iron content increasing. The adsorption of chloroactic and lead ionic in wate on the magnetic Bentonite was studied. The result is that the adsorption capability of magnetic Bentonite is equal with powder original Bentonite. Compared with active carbon, the adsorption capability of magnetic Bentonite on lead ionic is very high. The synthesized magnetic Bentonite can be easily separated from solution with magnetic