高等高分子物理与化学作业-配合物高分子研究报告.pptx

金属配位高分子 Polymer-metal complex 汇报人：康萌萌 导 师：付国东 专 业：材料物理与化学 日 期：2016年4月11日 目 录 CONTENTS Haemoglobin Fe(II) complex Chlorophyll Mg(II) complex 1 Coordination polymer For instance in 1963, the Nobel prize in chemistry was awarded jointly to K. Ziegler of the Max Plank Institute, in Germany and G. Natta of the University of Milan in Italy for developing a new metal complex catalyst containing aluminium and titanium. 1 Coordination polymer 1 Coordination polymer Polymer-metal complexes comprising an organic polymer containing coordinating sites, complexed with metals. A polymer ligand contains anchoring sites like nitrogen, oxygen or sulphur obtained either by polymerization of monomer possessing the coordinating site or by a chemical reaction between a polymer and a low molecular weight compound having coordinating ability 2 Classification of polymer–metal complexes) Complexation of polymeric ligand with metal ion Pendant metal complexes Inter/intra-molecular bridged polymer–metal complexes Complexation of multi- functional ligands with a metal Polymerization of metal containing monomer Polymer-metal complexes Linear coordinated polymers Network-coordinated polymers 2.1 Complexation of polymeric ligand with metal ion (b) monodentate (a) multidentate ligands (c) bridged structure 2.1.1 Pendant metal complexes 2.1.2 Inter/intra-molecular bridged polymer–metal complexes 2.1 Complexation of polymeric ligand with metal ion 2.2 Complexation of multifunctional ligands with a metal (a) copper complex of poly(thiosemicarbazide (氨基硫脲)) (b) copper complex of poly(a-amino acids) 2.2.1 Linear coordinated polymers 2.2.2 Network-coordinated polymers Complexation of multifunctional ligands with a metal 2.2 Complexation of multifunctional ligands with a metal Polyphthalocyanato (酞菁) copper(II) Polyporphyrinato (卟啉) copper(II) 2.3 Polymerization of metal containing monomer Cu-complex with Schiffbase ligand containing vinyl group methacrylato–penta