液相法合成高容量LiFePO4C复合正极材料.pdfVIP

化 ? 238 ? 工 进 展 CHEMICAL 卧IDUSTRY AND ENG卧mERING PROGRESS 2007 年第 26 卷第 2 期 j夜相法合成高容量 LiFeP04/C 复合正极材料 韩恩山，魏子海， 刘援，康红欣 (河北工业大学化工学院应用化学系， 天津 300130 ) 摘要: 采用液相共沉淀法合成了纯相橄榄石型LiFepo4f口LiFePOJC复合正极材料. 利用原子吸收(AAS)、精线 衍射仅RD)、 扫描电镜(SEM)、振实密度测定等方法对其进行表征， 并组装成电池研究其电化学性能。 结果表明: LiFeP04和LiFePOJC都具有单一的橄榄石型晶体结构， 且前者的振实密度可达1.67 g!cm2，掺碳后制成的LiFePOJC 振实密度有所降低， 但充放电平台非常平稳. 与纯相LiFeP04相比， LiFePOJC具有更高的放电比容量和循环性能， 室温下以0.2 mA!cm2和0.4 mAlcm2电流密度充放电，首次放电比容量分别达到158 . 1 mA . h/g 、 150.0 mA . hlg. 充 放电循环20次后放电比容量仍分别保持在154.2 mA . h/g, 137.2 mA . h/.各 关键词:钮离子电池; LiFeP04!C; 共沉淀法;复合正极材料 中图分类号:币，f 912.9 文献标i只码:A 文章编号: 1000 - 6613 ( 2007 ) 02 - 0238 - 04 Synthesis of high capacity LiFeP04/C composite cathode material by liquid-state method HAN Enshan , WEI Zih邸， LIU Yu侃 ， KANG Hongxin CDepaltment of Applied Chemis町， School of Chemical Engilleeling and Technology , Hebei University ofTechnology, Tianjin 300130 , China) Abstract : Pure phase olivine-type LiFeP0 4 and composite cathode material LiFePOJ C were synthesized by the liquid-state co-precipitation method. The propelties ofLiFeP04 and LiFePOJC were systemically studied via 也e methods of AAS , XRD, SEM, tapped density, etc. The electrochemical properties were tested by using analogous assembled cells. The results showed that LiFeP04 and LiFePOJC were bo也 simple pure phase olivine-type and 也e tapped density of the former could reach 1.67 g/cm3. After carbon coating, the tapped density decreased a little but had a good charge-discharge voltage plat臼u. Compared with pure phase LiFeP0 4 LiFePOJ C had better discharge capacities and excellent cycle perfonnance, and its f11st discharge capaεity was 158.1 mA ? h/g at 0.2 mAlcm 2 and even a1 0.4 mAlcm 2 at room temperature, LiFePOJC also had high discharge capacity of 150.0 mA ? h/g. After 20 times cycling, the specific capacities were 154.2 mA ? h/g, 137.2 mA ? h/g respectively. Key words: Li-ion battery; LiFePOJC; co-precipitation; composite cathode material LiFeP04作为21世纪最具潜力的铿离子二次电