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Adsorption of copper, cadmium, lead and zinc onto a synthetic.pdf

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Adsorption of copper, cadmium, lead and zinc onto a synthetic

Journal of Colloid and Interface Science 399 (2013) 99–106Contents lists available at SciVerse ScienceDirect Journal of Colloid and Interface Science www.elsevier .com/locate / jc isAdsorption of copper, cadmium, lead and zinc onto a synthetic manganese oxide Lo?c Della Puppa a,b, Michael Komárek a,?, Fran?ois Bordas b, Jean-Claude Bollinger b, Emmanuel Joussein b aDepartment of Environmental Geosciences, Faculty of Environmental Sciences, Czech University of Life Sciences Prague, Kamy?cká 129, Prague 6 – Suchdol, 165 21, Czech Republic bGroupement de Recherche Eau Sol Environnement, Université de Limoges, Faculté des Sciences, 123 Avenue Albert Thomas, 87060 Limoges, Francea r t i c l e i n f o Article history: Received 18 December 2012 Accepted 14 February 2013 Available online 27 February 2013 Keywords: Manganese oxide Sorption Divalent metal cations Birnessite0021-9797/$ - see front matter 2013 Elsevier Inc. A /10.1016/j.jcis.2013.02.029 ? Corresponding author. Fax: +420 234 383 778. E-mail address: komarek@fzp.czu.cz (M. Komárek)a b s t r a c t Due to its simple and inexpensive synthesis, a new amorphous hydrous manganese oxide (AMO) has been studied as a possible chemical stabilizing agent for soils contaminated with metals. Preliminary experiments evaluating the stability of AMO in pure water have reported only minor dissolution (5.70% and 0.24% depending on the w/v ratio). Sorption kinetics have shown fast metal adsorption, espe- cially for Pb. The sorption capacities of AMO for Cu, Cd, Pb, and Zn have been described and compared with synthetic birnessite for pH 4 and 5.5. Both oxides show similar sorption capacities at pH 4 despite the fact that birnessite characteristics (pH of zero point charge, specific surface area and cation exchange capacity) are more favorable for metal sorption. Moreover, the pH adsorption-edges show that the AMO is more pH-dependent than birnessite. 2013 Elsevier Inc. All rights reserved.1. Introduction The behavior and mobilit