石墨烯在锂电池的应用展望和发展前景.pptx

1 CIBF2014 石墨烯在锂离子电池中的应用研究进展 The progress in applications of graphene materials in Li-ion batteries 刘兆平 / LIU Zhaoping 中国科学院宁波材料技术与工程研究所 Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences June 21, 2014 NIMTE NIMTE 2 Outline ? ? ? ? Introduction Preparation of graphene Application of graphene-based nanocomposites for Batteries Conclusions and outlooks NIMTE 3 carrier mobility electrical conductivity thermal conductivity strength specific surface area light transmittance 1/300 of c 106 S/cm 4000 W/m K 130 GPa 2600 m2/g 97.3% Introduction Introduction transistor flexible display touch screen energy storage conductive plastic structural materials graphene graphite NIMTE Scalable Low Cost Production Technique 4 Practical Application Technolog y 5 ? ? ? ? ? high conductivity large surface area 2D nanostructure high strength low density Introduction Lithium ion battery Supercapacitor NIMTE Li-air battery Li-S battery NIMTE 6 Outline ? ? ? ? Introduction Preparation of graphene Application of graphene-based nanocomposites for Batteries Conclusions and outlooks NIMTE graphene oxide Chem. Commun. 2010, 46(15), 2511. 7 graphene graphite graphite oxide graphene oxide graphene oxidation delamination Modified preparation of reduced graphene chemical reduction shaking nonionic surfactant ultralarge sheets stable, high conc. suspension Samples Conductivity(S/cm) asprepared 0.25 o annealedat500C 100 o annealedat800C 400 NIMTE C=O C-O sp2C as prepared annealed at 800oC annealed at 500oC C/O = 8/1 Modified preparation of reduced graphene graphene foam Chem. Commun. 2010, 46(15), 2511. 8 NIMTE 9 ? Highly viscous suspension ? Difficulties in purification ? Large quantities of corrosive wastes Modified preparation of reduced graphene Scale-up attempts 200g/batch Better Solutions? MeanThickness LateralSize Apparent Density CarbonContent Electrical Conductivity SpecificSurface Area ～3nm 5-10μm 3 0.05-0.1g