氧气底吹铜熔炼渣中多组元造渣行为及渣型优化.pdfVIP

第 25卷第 6期 中国有色金属学报 2015年 6月 Volume 25 Number 6 The Chinese Journal of Nonferrous Metals June 2015 文章编号：1004-0609(2015)06-1678-09 氧气底吹铜熔炼渣中多组元造渣行为及 渣型优化 王亲猛 1, 2，郭学益 1, 2，田庆华 1, 2，廖立乐 1, 2，张永柱 1, 2 (1. 中南大学 冶金与环境学院，长沙 410083； 2. 中南大学 中国有色金属工业清洁冶金工程研究中心，长沙 410083) 摘 要：通过分析氧气底吹铜熔炼过程产生的铁硅型工业铜渣中 SiO2、Fe、S、Cu、CaO等组元含量变化趋势， 结合冶金过程原理，研究上述各组元造渣行为及组元含量相互间的映射关系，并进行渣型优化。结果表明：SiO2、 Fe、S、Cu及 CaO等组元的造渣行为具有相互关联性，且各组元与 Cu造渣行为的关联性由强到弱的顺序依次为 S、m(Fe)/m(SiO2)、SiO2、Fe。同时，SiO2和 Fe含量对 Cu含量的耦合作用较明显，随 SiO2含量升高，Fe含量降 低，Cu含量呈降低趋势。通过渣型优化，渣中 SiO2含量为 26.5%~28%、Fe含量为 38.5%~40%(质量分数)，该渣 型的流动性较好，理论上底吹熔炼渣含 Cu可降低到 2.5%(质量分数)以下。 关键词：铜冶炼；氧气底吹；铜渣；组元行为；渣型优化 中图分类号：TF811 文献标志码：A Multicomponent slagging behavior and constitution optimization of slag in copper oxygen bottom blowing bath smelting process WANG Qin-meng1, 2, GUO Xue-yi1, 2, TIAN Qing-hua1, 2, LIAO Li-le1, 2, ZHANG Yong-zhu1, 2 (1. School of Metallurgy and Environment, Central South University, Changsha 410083, China; 2. Cleaner Metallurgical Engineering Research Center, Nonferrous Metal Industry of China, Central South University, Changsha 410083, China) Abstract: The multicomponent slagging behavior and mapping relationship of SiO2, Fe, S, Cu and CaO and slag constitution optimization were investigated by analyzing SiO2, Fe, S, CaO and Cu content variation trends of industrial iron silicate slag in copper oxygen bottom blowing bath smelting (BBS) process, combined with metallurgical process principles. The results show that the slagging behaviors of SiO2, Fe, S, Cu and CaO have certain correlation, and the correlation sequence with Cu slagging behavior is S, m(Fe)/m(SiO2), SiO2, Fe. The rule of coupling interaction between SiO2 and Fe to Cu is sensible. Cu content increases with the increase of SiO2 and the decrease of Fe. Through optimizing the slag, SiO2 and Fe contents in slag are 26.5%−28% and 3