水溶性环氧树脂对注凝成型Al2O3泡沫陶瓷结构和性能的影响.pdfVIP

第 30 卷 第 10 期 无 机 材 料 学 报 Vol. 30 No. 10 2015 年 10 月 Journal of Inorganic Materials Oct., 2015 收稿日期: 2015-03-20; 收到修改稿日期: 2015-06-10 基金项目: 上海市科学技术委员会(14XD1421200) Science and Technology Commission of Shanghai Municipality (14XD1421200) 作者简介: 张小强(1988–), 男, 硕士研究生. E-mail: 894186912@ 通讯作者: 王士维, 研究员. E-mail: swwang51@ 文章编号: 1000-324X(2015)10-1085-04 DOI: 10.15541/ji 水溶性环氧树脂对注凝成型 Al2O3 泡沫陶瓷结构和性能的影响 张小强, 孙 怡, 岛井骏藏, 王士维 (中国科学院 上海硅酸盐研究所, 上海 200050) 摘 要: 以异丁烯和马来酸酐共聚物(PIBM)为分散剂和凝胶剂, 同时添加两种表面活性剂, 通过机械发泡和注凝 成型工艺制备高气孔率 Al2O3 泡沫陶瓷, 并研究了 DE211 环氧树脂对 Al2O3 泡沫陶瓷结构和性能的影响。结果表 明, 该工艺能够制备气孔率达 92.4%的 Al2O3 泡沫陶瓷。随着 DE211 环氧树脂的加入, 泡沫陶瓷的气孔率略有降 低, 抗压强度由 0.5 MPa 提高到 3 MPa, 平均气孔尺寸由 582 μm 下降到 331 μm, 孔壁塌陷少。这归因于 DE211 环氧树脂的环氧基能够与 PIBM 的酸酐发生反应, 加快凝胶固化速度, 从而有利于稳定泡沫结构。 关 键 词: Al2O3 泡沫陶瓷; 环氧树脂; 表面活性剂; 注凝成型; 机械发泡 中图分类号: TQ174 文献标识码: A Effect of Water-soluble Epoxy Resin on Microstructure and Properties of Porous Alumina Ceramics by Gel-casting ZHANG Xiao-Qiang, SUN Yi, SHIMAI Shun-Zo, WANG Shi-Wei (Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China) Abstract: Porous alumina ceramics with high porosity were fabricated by gel-casting and mechanical foaming. Here, PIBM, a co-polymer of isobutylene and maleic anhydride, was used as both dispersant and gelling agent, and two kinds of surfactants were selected as the foaming agent. Then, the effect of DE211 (a water-soluble ep- oxy resin) on the microstructure and properties of porous alumina ceramics were studied systematically. The re- sults showed that porous alumina ceramics with maximum porosity up to 92.4% was achieved by this method. With addition of DE211 epoxy resin from 0 to 0.5wt%, porosity of porous alumina ceramics slightly decreased and mean pore size decreased from 582 μm to 331 μm, but compressive strength increased from 0.5 MPa to 3 MPa. Besides, there is hardly collapse of cell wall in the porous ceramics. These