石墨烯对水泥净浆力学性能及微观结构的影响.pdfVIP

第 47卷 第 12期 2 0 1 5年 12月 哈 尔 滨 工 业 大 学 学 报 JOURNAL OF HARBIN INSTITUTE OF TECHNOLOGY Vol. 47 No. 12 Dec. 2015 doi:10.11918 / j.issn.0367-6234.2015.12.005 石墨烯对水泥净浆力学性能及微观结构的影响 曹明莉，张会霞，张 聪 (大连理工大学 土木工程学院,116024 辽宁 大连) 摘 要: 为改善石墨烯纳米材料疏水性,采用硝酸氧化和超声波法制备石墨烯分散悬浮液,考察石墨烯质量分数对水泥净浆 力学性能及其微观结构的影响,探讨石墨烯的增强增韧作用机制,结果表明,水泥基复合材料的抗压、抗折强度随着石墨烯质 量分数的增加呈先增大后减小的趋势,且最佳质量分数为水泥质量的 0.02 %.通过 SEM和 FT-IR对硬化水泥石的结构进行表 征,发现石墨烯能够促进水泥水化产物的生长,改变水化晶体的形状、尺寸,使其有形成完整、簇状的趋势,但并未与水泥发生 化学反应,改变其生成物类型. 关键词: 石墨烯；水泥净浆；力学性能；微观结构；模版效应 中图分类号: TU525 文献标志码: A 文章编号: 0367-6234(2015)12-0026-05 Effect of graphene on mechanical properties and microstructure of cement paste CAO Mingli, ZHANG Huixia, ZHANG Cong (School of Civil Engineering, Dalian University of Technology, 116024 Dalian, Liaoning, China) Abstract: Graphene suspension was prepared by nitric acid oxidation and ultrasonic to improve the hydrophobicity. Graphene suspension was added to cement to produce cement-graphene composite. The effect of graphene on mechanical properties and microstructure of cement paste was studied. In addition, the toughing mechanism of grapheme was also discussed, which provide theoretical and practical foundation for the study of graphene cement- based composite materials. With the increase of graphene content, the compressive and flexural strength of cement- based composite increased firstly then decreased, and the optimal additive amount is 0.02 wt%. The results from structural analysis of set cement by SEM and FT-IR indicated that graphene can promote the growth of the hydration products, change the shape and size of hydration crystal, but did not change its type through reacting with cement and graphene. Keywords: graphene; cement paste; mechanical properties; microstructure; template effect 收稿日期: 2014-12-02. 作者简介: 曹明莉(1971—),女,副教授,博士生导师. 通信作者: 张会霞,zhanghuixia199016@ 163.com. 自 2004年英国曼彻斯特大学物理学教授 Geim 和 Novoselov通过微机械剥离方法得到单层石墨烯 (graphene nanosheets,GNs)以来,对 GNs 的研究及 其应用一直是国际新材料领域的研究热点[1] .狭义 上只有单层石墨才属于石墨烯,而现在所说的石墨 烯