Infrared absorption method of V ascorbic acid in aqueous solution and ionic liquid 13 methyl ethyl imidazolium tetrafluoroborate The electrochemical behavior.docVIP

 PAGE \* MERGEFORMAT 12 Infrared absorption method of V ascorbic acid in aqueous solution and ionic liquid 13 methyl ethyl imidazolium tetrafluoroborate The electrochemical behavior [Abstract] V electrochemical and infrared absorption of the ascorbic acid method (AA) in aqueous and ionic liquid, 1-ethyl-3-methylimidazolium (EMIMBF4) The electrochemical behavior. AA in EMIMBF4 in aqueous solution with the same irreversible oxidation into dehydroascorbate (DHAA). situ FTIR spectroscopy results show that, DHAA in the water rapidly hydrolysis, and in EMIMBF4 in the more stable. In EMIMBF4 in, AA carbonyl peak at 1739 cm-1 处, DHAA the carbonyl peak appears in the 1785 cm-1 Office, they are compared to the free state of the carbonyl group had red shift. reason may be that between AA and DHAA easy to form hydrogen bonds with the EMIMBF4, or AA itself formed a hydrogen bond, DHAA to form dimers exist. [Keywords:] ascorbic acid, ionic liquid, on-site electrochemical infrared spectroscopy, infrared absorption method V 1 Introduction Ascorbic acid (AA) is a wide range of physiologically active substances [1], chemical stability is poor, the water can easily be oxidized in the air, see the light easily decomposed; electrochemical reaction activity is sensitive, in different chemical environments, such as different electrode and the pH solution , has a different reaction mechanism. AA at different metal electrodes on the surface of the electro-oxidation mechanism and kinetics of many reports [2 ~ 12]. Aldaz et al [8 and 12] in the Pt, Ga, Au and Hg electrode surface electro-oxidation process were found to have radical anion intermediates exist. speculated AA at pH lt;8 when the reaction mechanism. In recent years, ionic liquids as chemical stability, electrical activity can be dissolved ionic conductivity of the material and has become a new kind of solvent, can be used to study the electrochemical behavior [13, 15]. In this study, 1-ethyl-3 methylimidazole (