Microwave-based macroporous resin together Isobutyl cinnamate catalyzed green synthesis of new technology.docVIP

 PAGE \* MERGEFORMAT 3 Microwave-based macroporous resin together Isobutyl cinnamate catalyzed green synthesis of new technology Author: Kwong Shou-min, XUE Ping, Su Xue Qun, Wang Jie Qun, Cao happy, Laihong Juan, Li Yu [Abstract] Objective To study the microwave  macroporous resin acid catalyzed synthesis of a new technology Gui. Method a certain amount of cinnamic acid and a certain amount of isobutyl ester, in different conditions, the macroporous resin as a catalyst for microwave synthesis experiments. Results cinnamic acid 2 g, acid-alcohol molar ratio of 1:7, catalyst amount 30%, microwave power 600 W, microwave temperature of 115 ℃ , microwave time of 14 min, conversion rate was 89.3%. Conclusion Microwave  catalyzed synthesis of macroporous resin, isobutyl cinnamate technology, is fast, energy-saving, environmentally friendly green synthesis of new process. [Keywords:] cinnamic acid, isobutyl; microwave synthesis; macroporous resin; catalytic Abstract: Objective The microwave assisted synthesis (MAS) was integrated with macroporous resin catalysis (MRC) to prepare isobutyl cinnamate from cinnamic acid.MethodsThe preparation processes were investigated under different conditions.ResultsThe optimum synthetic conditions were 2 g cinnamic acid, microwave power was 600 W, reaction temperature was 115 ℃ , reaction time was 14 min, mass percent of macroporous resin was 30%, the molar ratio of cinnamic acid to isobutyl alcohol was 1:7, and the yield of the new process was 89.3%. ConclusionThe new developed technology is rapid, economical and has no pollution. Keywords:: Isobutyl cinnamate; Microwave assisted synthesis; Macroporous resin; Catalysis Isobutyl cinnamate as a colorless liquid with a fresh fruit flavor, is an important ester compounds, commonly used in daily chemical consumption of spices and spices [1]. Synthesis of the current cinnamate mainly traditional heating synthesis method, the catalyst is mainly used in concentrated sulfuric acid