Monodisperse hydrophilic polymer matrix Preparation and Application of Cationic column.doc

 PAGE \* MERGEFORMAT 16 Monodisperse hydrophilic polymer matrix Preparation and Application of Cationic column Study: GONG Bo-Lin Hu Jia Leina sandwiches Yang Chunxia [Abstract] made #8203;#8203;5.0 μm hydrophilic monodisperse crosslinked macroporous glycidyl methacrylate microspheres as matrix synthesis of a new type of weak acid cation CHROMATOGRAPHY. Use of methane sulfonic acid eluent at a flow rate To 1.0 mL / min, the 6 kinds of inorganic cations (Li +, Na +, NH +4, K +, Mg2 +, Ca2 +) and organic amines were well separated. The effects of eluent type, concentration and flow rate on the six kinds of inorganic cations the impact of separation, select the appropriate chromatographic conditions. 6 ions measured in a certain concentration range with good linearity and low detection limit. Cassia it for the analysis of cations tea, 4 kinds of ion completely separated in 20 min, the recoveries of each ion in 96% -107%. The separation column with Dionex IonPac  CS12A column close to the goods, but the analysis time by 44 min. [Keywords:] Hydrophilic monodisperse resins, weak cation chromatography, cation, organic amines, Cassia tea 1 Introduction Ion chromatography (IC) is developed in the 20th century, a 70 chromatography, mainly for the analysis of ionic compounds and separation. Since 1975, Small et al [1] After the ion chromatography, IC method gradually in the environment [2], food [3], medicine [4], oil and chemical [5] and the fields of agriculture has been widely used. to silica and organic polymer matrix, the filler is a filler used ion chromatography. In recent years, Fill in the silica gel as cation carriers, with synthesis of poly maleic acid double-team the stationary phase [6] to develop a more active, which is easy through the relatively large solute filling the holes with the stationary phase on the active site of contact, mass transfer rate, and high column efficiency, but the drawback is the narrow range of pH used, which to some