New dual-core Schiff Base Synthesis and Fluorescence Activity.docVIP

 PAGE \* MERGEFORMAT 9 New dual-core Schiff Base Synthesis and Fluorescence Activity Author: Zhang Mingqin Yuan Fang WU Qing Hu Qinghong Zeljko Lou [Keywords:] dual-core activity of Schiff base synthesis of fluorescent Abstract A novel binuclear Schiff base ligand (H4L) and its zinc (II) complexe has been synthesized from the reaction of N, N, N ‘, N’  tetra [2  (2  aminoethylamino) formylethyl] ethylene diamine and salicylaldehy  de, and characterized by elemental anaysis, 1HNMR, IR, UV  vis spectrophoto  metry and molar conductance.The fluorescence activities in DMSO of Schiff base ligand and zinc (II) complexe were studied. Keywords: binuclear schiff base; synthesis; fluorescence activity Multi-core Schiff base metal complexes due to its antibacterial, anti-cancer and anti-virus, biological activity, catalytic, magnetic materials, semiconductor and bio-inorganic chemistry and other fields increasingly important role in causing people’s attention [1 ~ 6]. Has been the formation of dual-core or multi-core Zhiyu complexes, require a favorable ligand and central ion, such as high charges, with more than a pair of lone pair electrons and can play the role given to body bridging atoms, as well as the appropriate experimental conditions and so on. In this study, the synthesis of a flexible chain of N, N, N ‘, N’  4 [2  (2  amino-B-amino)-formyl-ethyl] ethylenediamine to form links with the eight-tooth salicylaldehyde Schiff base compounds ( Figure 1), which contains several elements to give body atoms (N, O), conducive to the formation of polydentate Schiff base compounds. An experimental part of the 1.1 Instrument and reagents Perkin  Elemer 240-type elemental analyzer; Bio  Rad-based Fourier transform infrared spectrometer (4000 ~ 400cm-1, KBr tablet method); Ry  2-type melting point instrument (thermometer uncorrected); Mercury VX 300 NMR instrument (300 MHz, TMS internal standard, DMSO  d6 as the solvent); UV  256FW UV 