Two dimensional monolayer gold Construction and application of bio-electrochemical_0.docVIP

 PAGE \* MERGEFORMAT 20 Two dimensional monolayer gold Construction and application of bio-electrochemical Of: Hou Dongmei Xiao Lei Wang Xueying Yin Chi Van [Abstract] using Langmuir Blodgett (LB) technique in indium tin oxide (ITO) electrode was prepared by two dimensional gold (nano Au) monolayer, characterized by scanning electron microscopy, two dimensional gold monolayer. The experimental results show that : surface pressure of 28 mN / m, the availability of good dispersion, the shape and uniform rules of two-dimensional spherical gold nanoparticle monolayer. LB was prepared by myoglobin (Mb) film and fixed in the second dimensional monolayer modified gold electrode surface of the myoglobin direct electrochemical behavior of LB films. The results show that: gold nanoparticles can effectively accelerate the electron transfer of myoglobin, the electron transfer rate of 1.415 s-1 . [Keywords:] Au monolayer, Langmuir Blodgett technology, myoglobin, electron transfer rate 1 Introduction Small size of nanoparticles, surface effect, quantum size effect and macroscopic quantum effects in nano-particles as a result of the thermal, magnetic, light-sensitive properties different from the conventional particle, which makes it has broad application prospects. Because gold nanoparticles have a more large surface area, surface atoms of the great remaining bonding capacity makes it easier for gold nanoparticles aggregate, Shen together, so it must be modified and protection of its [1,2], in order to achieve the gold nanoparticle size, size distribution and assembly dimension control. which two-dimensional ordered array of nano-gold particles exhibit unique electrical, magnetic and optical properties, in optical devices, ultra-high density information storage and nano-electronic devices, etc. have significant application prospects [3, 4]. Currently, two dimensional array of material assembled monolayer method LB technique [5,6], self-assembly [7] and electro