利用石灰石连续分离烟气中CO2的双流化床实验研究.pdfVIP

中国工程热物理学会 燃烧学 学术会议论文 编号：094311 利用石灰石连续分离烟气中 CO2 的双流化床实验研究 房凡，李振山，蔡宁生 (清华大学热能工程系·热科学与动力工程教育部重点实验室，北京 100084) (联系电话：010；E-mail ：fangf06@mails.tsinghua.edu.cn) 摘要：控制和减缓电力生产中CO2 的排放对于解决大气温室效应和全球变暖具有显著的作用。钙基吸 收剂循环煅烧/碳酸化法是捕集燃煤电厂烟气中CO2 的一种潜在技术，利用双流化床反应器实现烟气中 CO2 连续高效捕集是此技术应用到实际的关键。本文利用天然石灰石，采用50kW 双流化床试验装置， 连续捕集烟气中的CO2 。试验结果表明，所采用的的双流化床反应器可以实现两个反应器中物料连续 稳定的交换，连续长时间高效捕集烟气中的CO2 ，捕集效率超过90%，最终证明利用钙基吸收剂循环 煅烧/碳酸化法捕集烟气中CO2 的技术是可行的。 关键词：双流化床反应器；煅烧；碳酸化；CO2捕集 Experiment Research on CO2 Capture from Flue gases Using Interconnected Fluidized Bed Reactors with Limestone Fang Fan, Li Zhen-shan, Cai Ning-sheng (Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Thermal Engineering, Tsinghua University, Beijing 100084, China ) Abstract: Reducing the CO2 emissions from power plant flue gases will have the potential to make a significant contribution to mitigate global warming and green house effect. Carbonation/calcination reaction cycles (CCRs) with Ca-based sorbents are a promising option for the capture of CO2 from power plant flue gases. To fulfill the function of multiple CCRs for CO2 capture using the interconnected fluidized bed reactors is the foundation to make CCRs to be practical application. The continuous CO2 capture experiment was carried out in a 40kW interconnected bubbling fluidized bed reactors in this work. The experimental results indicated that the dual fluidized bed reactors could achieve stable operation and continuous solid circulation between the carbonator and calciner, and the steady state