Dying to find the source – the quantitative use of rhodamine WT as a proxy for soluble point source pollutants in closed pipe surface drainage networks.docVIP

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Dying to find the source – the quantitative use of rhodamine WT as a proxy for soluble point source pollutants in closed pipe surface drainage networks.doc

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Dying to find the source – the quantitative use of rhodamine WT as a proxy for soluble point source pollutants in closed pipe surface drainage networks

Hydrol.EarthSyst.Sci.Discuss.,6,4535–4562,2009 /6/4535/2009/ ?Author(s)2009.Thisworkisdistributedunder theCreativeCommonsAttribution3.0License. Hydrology and Earth System Sciences HESSD 6,4535–4562,2009 Discussions Dyingto?ndthe source–the quantitativeuseof rhodamineWT PaperspublishedinHydrologyandEarthSystemSciencesDiscussionsareunder open-accessreviewforthejournalHydrologyandEarthSystemSciences C.H.Minesetal. Dyingto?ndthesource–thequantitative useofrhodamineWTasaproxyfor solublepointsourcepollutantsinclosed pipesurfacedrainagenetworks C.H.Mines,A.Ghadouani,andG.N.Ivey TitlePage Abstract Conclusions Tables Introduction References Figures J J I I SchoolofEnvironmentalSystemsEngineering,TheUniversityofWesternAustralia,35 StirlingHighway(M015),Crawley,WesternAustralia,6009,Australia Back Close Received:14May2009–Accepted:25May2009–Published:23June2009 Correspondenceto:A.Ghadouani(anas.ghadouani@.au) FullScreen/Esc PublishedbyCopernicusPublicationsonbehalfoftheEuropeanGeosciencesUnion. Printer-friendlyVersion InteractiveDiscussion 4535 Abstract HESSD RhodamineWT(RWT),axanthenedye, mayserveasaproxyforsolublepollutants within quantitative tracing studies investigating point source contaminant transport. This study quanti?ed the e?ects of altering the concentration, pH, temperature and salinityofaRWTsolutiononthedetected?uorescenceofRWTwithinthelaboratory priortoa?eldreleaseofRWTwithinaclosedpipeurbandrainagenetwork. AllRWT solutionsexhibitedstabilityand10%variationfromtheexpectedconcentrationover athirteenhourlaboratorystudyperiod;pHrelatedquenchingofRWT?uorescenceof upto14.9%wasobservedforsolutionswithpH3.9;andincreasingsalinityofRWT 10 solutionwasfoundtohaveanegligiblequenchinge?ect. Indirectcontrasttoprevious studiesRWT?uorescencewasfoundtodirectlycorrelatewithtemperatureofsolution, andatemperaturecorrectionfactorwasdeterminedandtested. Ifthesee?ectswere combinedinanadditivemanner,themaximumpotentialunderestimationandoveres- timationofRWTconcen