催化裂化装置腐蚀失效分析与实验室模拟实验研究.docVIP

催化裂化装置腐蚀失效分析与实验室模拟实验研究 JournalofMechanicalStrength机械强度2004,26(6):691～695 FAILUREANALYSISOFCORROSIONCRACKINGAND SIMULATINGTESTFORFCCU 陈　华ΞΞ　李　明　　李晓刚111,2Ξ　　杨锦文　　陈鸣皋33 (1.北京科技大学腐蚀与防护中心,北京市腐蚀、磨蚀与表面技术开放实验室,北京100083) (2.中国科学院金属研究所腐蚀与防护国家重点实验室,沈阳110015) (3.中国石油化工股份有限公司九江分公司,九江332004) 　YANGJinWen　CHENMingGao(1.CorrosionandProtectionCenter,UniversityofScienceandTechnologyBeijing, TheKeyLaboratoryofCorrosion,ErosionandSurfaceTechnologyofBeijing,Beijing100083,China) (2.StateKeyLaboratoryofCorrosionandProtection,InstituteofMetal, ChineseAcademyofSciences,Shenyang,) (3.JiujiangPetrochemicalCompany,China,China) 摘要　通过对催化裂化再生器在NOx2SOxH2O、硬度测定、化学成分分析、介质分析、金相检验、,在NOx2SOx2H2O烟,发生硝酸盐应力腐蚀开裂。实验室进行的现场模拟实验所得的,进一步论证了现场装置的开裂是由硝酸盐应力腐蚀开裂引起的。NOx2SOx2H2O烟气体系中产生的应力腐蚀开裂进行预测,并为进一步研究有效的防护对策提供科学的依据。 关键词　应力腐蚀　催化裂化装置　露点　失效 中图分类号　TG172.3　TG115.5 Abstract　Somenondestructivedetectionmethods,hardnessmeasurement,analysisofchemicalcompositions,medium,fracturesurfaceandcorrosionproducts,opticalmicroscopywereusedtoinvestigatethereasonofthecrackingintherecycledsystemoffluidcata2lyticandcrackingunit(FCCU).Theanalysisresultsshowedthatthecrackwerestresscorrosioncrackingwhicharecausedbynitrate,andweregeneratedtogetherwiththeacidiccorrosivemediumbelowdewpointtemperatureinmixingfumeNOx2SOx2H2Oenvironment.Theresultofsimulatingtestinlaboratorydisplayedthesamecharacteristicsasthatoffailuredinstrumentsintheequipment.ItcanbefurtherprovedthatstresscorrosioncrackingcausedbynitratewasthemajorreasonofcrackingforFCCU.SomesuggestionsareproposedtopreventtheoccurrencesofstresscorrosioncrackingofFCCU. Keywords　Stresscorrosion;Fluidcatalyticcrackingunit;Dewpoint;Failure Correspondingauthor:CHENHua,E2mail:yunda@,Tel:+86210262333931,Fax:+86210262333931CHENHua　LIMing　LIXiaoGang111,233 Thisprojectsupportedbythe973ScienceFoundationofChina(No.199900650)andCenterofTechnique,ChinaPetrochemicalCorporationofChina. Manuscriptreceiveinrevisedform20031124