气相色谱法（GC-FPD）快速测定蔬菜、水果中18种有机磷.PDFVIP

安徽农业大学学报, 2013, 40(6): 1054-1058 Journal of Anhui Agricultural University 网络出版时间：2013-4-26 15:37:04 [URL] /kcms/detail/34.1162.S1537.017.html 气相色谱法 （GC-FPD ）快速测定蔬菜、水果中 18 种有机磷农药残留 1 2* 2 1 汤 婕 ，汤 锋 ，岳永德 ，花日茂 (1. 安徽农业大学资源与环境学院，合肥 230036 ；2. 国际竹藤中心，北京 100080) 摘 要：建立 18 种有机磷农药在青菜、黄瓜、萝卜、苋菜、辣椒 5 种蔬菜和桃子、苹果 2 种水果中残留量快 速检测方法。样品中有机磷农药采用乙酸乙酯提取，取适量样品提取液直接用 GC-FPD 检测，低浓度的添加回收 样品浓缩至一定体积后进样。18 种供试农药的定量限（LOQ ）在2 ～30 μg·kg-1 范围内，检测限（LOD ）在3.6×10-10 g ～5.5×10-12 g 范围内，回收率在 70.25% ～120.50%，变异系数在0.65% ～30.70% ，满足农药残留分析要求。 关键词：蔬菜；水果；有机磷农药多残留分析；GC-FPD 中图分类号：X592 文献标识码：A 文章编号：1672−352X (2013)06−1054−05 Rapid detection of 18 organphosphorus pesticide multiresidue in vegetables and fruits with GC-FPD 1 2 2 1 TANG Jie , TANG Feng , YUE Yong-de , HUA Ri-mao (1. School of Resources and Environment, Anhui Agricultral University, Hefei 230036; 2. International Center for Bamboo Rattan, Beijing 100080) Abstract: A method for detecting 18 organphosphorus pesticide residues in vegetables and fruits by GC-FPD was developed. The samples were extracted by ultrasonic extraction with ethyl acetate. The extracts were deter- -1 -10 mined by GC-FPD. The LOQ and LOD of 18 pesticides were in the range of 2 - 30 μg·kg and 3.6×10 g - -12 5.5×10 g, respectively. The fortified recoveries of 18 pesticides were from 70.25% to 120.50%, and the RSDs( relative standard deviation)were from 0.65% to 30.70