五氯苯酚光催化降解的影响因素分析.pdfVIP

学兔兔 化 工 进 展 2009年第28卷第5期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·899· 五氯苯酚光催化降解的影响因素分析 罗进飞 ，于洪锋 ，李 洪 ，李鑫钢 ( 天津大学化工学院，天津 300072： 精馏技术国家工程研究中心，天津 300072) 摘 要：研究者对海河流域水质的调查发现，五氯苯酚是检出量最多的持久性有机污染物，因此控制五氯苯酚污 染对控制海河持久性有机污染起着非常关键的作用。为此本文对五氯苯酚光催化降解的影响因素进行实验研究和 分析，首先对O2、H2O2、K2S2O8三种外加氧化剂在环境、工艺和经济三方面进行比较，研究表明o2(空气)是 较好的选择。通过正交实验对光催化降解五氯苯酚的操作条件pH值、流量、光强、催化剂用量进行研究，结果 表明，流量对光催化降解五氯苯酚的影响很小；光催化效果随着pH值得增加和光强的增加而增加；催化剂用量 对光催化降解五氯苯酚的影响存在峰值。 关键词：五氯苯酚；光催化降解；正交实验 中图分类号：TQ 453．2 1 文献标识码：A 文章编号：1000—6613(2009)05—0899—05 Analysis of influence factors of photocatalytic degradation of pentachlorophenol LUO Jinfei ，YUHongfeng ，LIHong ，LIXingang ’ ( School of Chemical Engineering and Technology，Tianjin University，Tianjin 300072，China： National Engineering Research Center for Distillation Technology，Tianjin 300072，China) Abstract： Studies on water quality of Haihe River Basin show that pentachlorophen0l(PCP)has become the major organic pollutant．As a result，to control the pollution of PCP has become vital for the pollution control in Haihe River Basin．The influence factors of photocatalytic degradation of PCP were studied and analyzed．First，photocatalysis assisted by three oxidants(O2，H202，K25208) was investigated in terms of techbnology，environmental impact and economy，and it showed that 02 was the optimal choice．The reaction conditions of photocatalysis，including pH of solution，circulation flow rate，light intensity，dosage of catalyst，were investigated with the o~hogonal method．The result showed that circulation flo