Anodic Stripping Voltammetric Determination of Nitrite Using Carbon Paste Electrode Modified with Chitosan英文文献资料.docVIP

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Anodic Stripping Voltammetric Determination of Nitrite Using Carbon Paste Electrode Modified with Chitosan英文文献资料.doc

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Anodic Stripping Voltammetric Determination of Nitrite Using Carbon Paste Electrode Modified with Chitosan英文文献资料

American Journal of Analytical Chemistry, 2011, 2, 284-288 doi:10.4236/ajac.2011.22035 Published Online May 2011 (http://www.SciRP.org/journal/ajac) Anodic Stripping Voltammetric Determination of Nitrite Using Carbon Paste Electrode Modified with Chitosan Ibrahim H. I. Habib Microanalytical Chemistry Lab, Applied Organic Chemistry Department, National Research Centre, Cairo, Egypt E-mail: ihihabib@ Received December 2, 2010; revised March 7, 2011; accepted May 14, 2011 Abstract A simple method for anodic stripping voltammetric determination of nitrite using carbon paste electrode modified with biomolecular chitosan, is described. In this method, the electrode is activated electrochemi- cally by scanning 5 replicates over the potential range from +500 to +1400 mV immersing in 0.5 M HCl so- lution. Following this step, the nitrite sample containing 0.1 M KCl is pre-concentrated on the activated elec- trode at +500 mV for 30 s. The deposited anions are then oxidized by different modes of sweep in the oxida- tion direction. Chemical and electrical parameters affecting the voltammetric measurements are optimized. The peak current is linear proportional to the NO?2 concentration within the range 0.41 - 4.1 μg/ml, with detection limit 0.187 μg/m using differential pulse mode. The relative standard deviation is 0.285 % for 2.46 μg/ml (five replicates). No interference is observed due to oxygen dissolved in the sample so that nitrogen purging is not needed in this case. The result obtained by the modified electrode is more accurate and selec- tive than the unmodified electrode. Keywords: Chitosan, Carbon Paste Electrode, Nitrite, Anodic Stripping Voltammetry 1. Introduction [24,25] have been used successfully for electrochemical oxidation of nitrite. Boron-doped diamond electrode [26] has also been applied for monitoring nitrite, but it needs special instruments not ever available elsewhere. Chitosan, on the other hand, is natural p