Application of tetratozilat meso-tetrakis (4-methylpyridil) porphyrin as effective sensor for metal cations in plasma-solution systems英文文献资料.docVIP

Vol.4, No.7, 461-465 (2012) Natural Science /10.4236/ns.2012.47062 Application of tetratozilat meso-tetrakis (4-methylpyridil)porphyrin as effective sensor for metal cations in plasma-solution systems Artur Vashurin , Svetlana Pukhovskaya , Ludmila Kuzmicheva , Yuliya Titova , 1* 1 2 2 3 Oleg Golubchikov 1 * 2 3 Department of Inorganic Chemistry, Ivanovo State University of Chemistry and Technology, Ivanovo, Russia; Corresponding Author: asv_87@mail.ru G. A. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russia Department of Organic Chemistry, Ivanovo State University of Chemistry and Technology, Ivanovo, Russia Received 29 May 2012; revised 28 June 2012; accepted 11 July 2012 ABSTRACT The simplest type of plasma-solution system is that with atmospheric pressure glow discharge with elec- trolyte cathode (Figure 1). Synthetic porphyrins have, in the last years, gained increasing interest in analytical chemis- try as unique reagents for the detection of metal ions. The porphyrin is a high sensitive chro- mogenic reagent. Porphyrins and their metal complexes generally exhibit characteristic sharp and intensive absorption bands in visible region. The region from 400 to 500 nm, which is called the Soret band, shows the most intensive ab- sorption, and molar absorptivities about 105 are often found. Soret band (400 - 500 nm) shows the most intensive absorption of these com- pounds, molar absorptivities often being about 105. The Soret band is widely used for spectro- photometric detection of metalloporphyrins. From the perspective of analytical chemistry, the por- phyrin ligand has turned out to be very versatile, and almost all metals have been combined with porphyrin. From this point of view several por- phy