Approximate Solution of Non-Linear Reaction Diffusion Equations in Homogeneous Processes Coupled to Electrode Reactions for CE Mechanism at a Spherical Electrode英文文献资料.docVIP

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Approximate Solution of Non-Linear Reaction Diffusion Equations in Homogeneous Processes Coupled to Electrode Reactions for CE Mechanism at a Spherical Electrode英文文献资料.doc

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Approximate Solution of Non-Linear Reaction Diffusion Equations in Homogeneous Processes Coupled to Electrode Reactions for CE Mechanism at a Spherical Electrode英文文献资料

American Journal of Analytical Chemistry, 2011, 2, 93-103 doi:10.4236/ajac.2011.22010 Published Online May 2011 (http://www.SciRP.org/journal/ajac) Approximate Solution of Non-Linear Reaction Diffusion Equations in Homogeneous Processes Coupled to Electrode Reactions for CE Mechanism at a Spherical Electrode Alagu Eswari, Seetharaman Usha, Lakeshmanan Rajendran * Department of Mathematics, The Madura College (Autonomous), Madurai, India E-mail: Received October 18, 2010; revised January 16, 2011; accepted January 21, 2011 * raj_sms@ Abstract A mathematical model of CE reaction schemes under first or pseudo-first order conditions with different diffusion coefficients at a spherical electrode under non-steady-state conditions is described. The model is based on non-stationary diffusion equation containing a non-linear reaction term. This paper presents the complex numerical method (Homotopy perturbation method) to solve the system of non-linear differential equation that describes the homogeneous processes coupled to electrode reaction. In this paper the approxi- mate analytical expressions of the non-steady-state concentrations and current at spherical electrodes for homogeneous reactions mechanisms are derived for all values of the reaction diffusion parameters. These approximate results are compared with the available analytical results and are found to be in good agreement. Keywords: Non-Linear Reaction/Diffusion Equation, Homotopy Perturbation Method, CE Mechanism, Reduction of Order, Spherical Electrodes 1. Introduction applications of microelectrodes of different shapes are impeded by lack of adequate theoretical description of their behavior. Microelectrodes are of great practical interest for quanti- tative in vivo measurements, e.g. of oxygen tension in living tissues [1-3], because electrodes employed in vivo should be smaller than the unit size of the tissue of inter- est. Microelectrodes having the geometr