Assessment of Toxicity of Some Penta- and Hexacoordinated Organotin(IV) and Tetracoordinated Tin(II) Complexes of Heterocyclic -Diketones英文文献资料.docVIP

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Assessment of Toxicity of Some Penta- and Hexacoordinated Organotin(IV) and Tetracoordinated Tin(II) Complexes of Heterocyclic -Diketones英文文献资料.doc

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Assessment of Toxicity of Some Penta- and Hexacoordinated Organotin(IV) and Tetracoordinated Tin(II) Complexes of Heterocyclic -Diketones英文文献资料

HindawiPublishingCorporation BioinorganicChemistryandApplications Volume2006,ArticleID60140,Pages1–4 DOI10.1155/BCA/2006/60140 AssessmentofToxicityofSomePenta-andHexacoordinated Organotin(IV)andTetracoordinatedTin(II)Complexesof Heterocyclicβ-Diketones AshaJain,1SanjivSaxena,1AudheshK.Rai,1andPrabhuN.Saxena2 1 2 DepartmentofChemistry,UniversityofRajasthan,Jaipur302004,India DepartmentofZoology,ToxicologyLaboratory,SchoolofLifeSciences,Dr.B.R.AmbedkarUniversity, Agra282004,India Received4May2004;Accepted9September2004 A number of penta- and hexacoordinated organotin(IV) complexes and tetracoordinated tin(II) complexes of compositions Me2SnCl[RCOC:CON(C6H5)N:CCH3](whereR=?CH3,?p?ClC6H4,and?C6H5),Me2Sn[RCOC:CON(C6H5)N:CCH3]2 (where R = ?CH3, and ?C6H5), and Sn(II) [RCOC:CON(C6H5)N:CCH3]2 (where R = ?p?ClC6H4 and ?C6H5 ) were screenedfortheirtoxicityagainstMuscadomestica(house?y).Ingeneral,organotin(IV)complexescontributemoretotheactivity thantin(II)complexes. Copyright?2006AshaJainetal.ThisisanopenaccessarticledistributedundertheCreativeCommonsAttributionLicense, whichpermitsunrestricteduse,distribution,andreproductioninanymedium,providedtheoriginalworkisproperlycited. INTRODUCTION EXPERIMENTS There has been considerable interest in the chemistry of penta- and hexacoordinated organotin(IV) complexes de- rived from various organic ligands due to their struc- tural and stereochemical aspects. In marked contrast to thewell-documentedchemistryoforganotin(IV)complexes [1–3], the number of reports available in the literature on the corresponding tin(II) [4, 5] complexes are rather scanty.Organotin(IV)complexesareputtouseinvarious ?elds[6–8]andexhibitpotentialbiologicalapplications[9– 11] such as insecticidal, fungicidal, and antitumor activi- ties. Inviewoftheinterestingresultsobtainedinourprevi- ouscommunication[12]dealingwiththetoxicityoforgan- otin(IV)andtin(II)complexesofheterocyclicβ-diketones, it was considered relevant to screen a series of penta- and hexacoordinate