Buffer standards for the physiological pH of the zwitterionic buffer 3-[N-tris(hydroxymethyl)methylamino]-2-hydroxypropanesulfonic Acid (TAPSO) From (278.15 to 328.15) K英文文献资料.docVIP

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Buffer standards for the physiological pH of the zwitterionic buffer 3-[N-tris(hydroxymethyl)methylamino]-2-hydroxypropanesulfonic Acid (TAPSO) From (278.15 to 328.15) K英文文献资料.doc

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Buffer standards for the physiological pH of the zwitterionic buffer 3-[N-tris(hydroxymethyl)methylamino]-2-hydroxypropanesulfonic Acid (TAPSO) From (278.15 to 328.15) K英文文献资料

Vol.2, No.4, 414-421 (2011) Journal of Biophysical Chemistry doi:10.4236/jbpc.2011.24048 Buffer standards for the physiological pH of the zwitterionic buffer 3-[N-tris(hydroxymethyl)methylamino]-2-hydroxypropan esulfonic acid (TAPSO) from (278.15 to 328.15) K Lakshmi N. Roy, Rabindra N. Roy , Blake M. Bodendorfer, Zachary M. Downs, * Stephen D. Rocchio, Jessica M. Stegner, Isaac B. Henson Hoffman Department of Chemistry, Drury University, Springfield, USA; Corresponding Author: rroy@ * Received 22 June 2011; revised 3 August 2011; accepted 24 August 2011. ABSTRACT values of 3-(N-morpholino)-2-hydroxypropanesulfonic acid (MOPSO) [3] from (278.15 to 328.15) K, including 310.15 K. The zwitterionic buffer 3-[N,N-bis(2-hydroxy- methyl)amino]-2-hydroxypropanesulfonic acid (DIPSO) [4] is also recommended for physiological use at (278.15 to 328.15) K. Regarding the current experiment the goal of the authors is to provide staunch pH values for the ampholyte 3-[N-tris(hydroxymethyl)-methylamino]-2-hy- droxypropanesulfonic acid (TAPSO) depicted by the foll- owing structure: This zwitterionic buffer, among others suggested by Bates and coworkers [5,10], may be used as biological buffers for biological media. The currently used NBS certified physiological phosphate primary standard buffer has recorded pH values of 7.415 and 7.395 at (298.15 and 310.15) K, respectively [5]. This phosphate buffer is comprised of KH2PO4 (0.008695 mol·kg–1) and Na2HPO4 (0.03043 mol·kg–1). Though it has been accepted by the NBS, problems still occur when using this particular phosphate buffer. The second dissociation constant, pK2, and re- lated thermodynamic quantities for TAPSO have been previously determined and reported from the temperatures (278.15 to 328.15) K. In the current study there are five buffer solutions without NaCl and five buffer solutions with NaCl present which yield an ionic strength (I = 0.1