Catalytic Dehydration of Glycerol under Mild Condition An Environmentally Benign Acrolein Production英文文献资料.docVIP

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Catalytic Dehydration of Glycerol under Mild Condition An Environmentally Benign Acrolein Production英文文献资料.doc

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Catalytic Dehydration of Glycerol under Mild Condition An Environmentally Benign Acrolein Production英文文献资料

Journal of Environmental Protection, 2010, 1, 201-205 1 doi:10.4236/jep.2010.12024 Published Online June 2010 (http://www.SciRP.org/journal/jep) Catalytic Dehydration of Glycerol under Mild Condition: An Environmentally Benign Acrolein Production ágnes Zsigmond , Péter Bata , Mónika Fekete , Ferenc Notheisz 1 1 1 2 1 Department of Organic Chemistry, University of Szeged, Szeged, Hungary; Organic Catalysis Research Group of the Hungarian 2 Academy of Sciences, University of Szeged, Szeged, Hungary. Email: {azsig, notheisz}@chem.u-szeged.hu, bata_peter@freemail.hu Received February 8 , 2010; revised March 29 , 2010; accepted March 31 , 2010. th th st ABSTRACT The increase of biodiesel production results in the accumulation of glycerol, which requires an increasing demand to- wards the study of chemical application of glycerol. Glycerol has to be transformed to other valuable chemicals, which can be used as starting materials for organic synthesis. With the final goal to find a reasonable solution for this prob- lem we have studied the dehydration of glycerol in liquid phase using a supported HPA catalyst and developed an en- vironmentally benign production of acrolein. Our method does not have any extreme conditions and produces a total conversion with high (93%) selectivity. Keywords: Consuming of Excess Glycerol, Production of Acrolein, Heterogeneous Method 1. Introduction Acrolein is an important chemical intermediate so it is very important to develop a sustainable and cost- effective production route via glycerol from biodiesel, which offers an alternative for the presently dominating petrochemical process based on propylene. The dehydration of glycerol to acrolein became