化学链燃烧中镍基载氧体与H2S反应机理研究.pdfVIP

中国工程热物理学会 燃烧学 学术会议论文 编号：094070 化学链燃烧中镍基载氧体与H2S 反应机理研究 * 高正平，沈来宏 ，肖 军, 吴家桦 (东南大学 热能工程研究所，南京 210096) (Tel: 025 Email:gzp030843@163.com) 摘要：采用热重分析与红外色谱分析(TGA-FTIR)相结合的方法，研究了NiO载氧体与高浓度CO与H2S 混合气的还原、硫化反应性。实验结果表明，随反应循环数增加，NiO载氧体的平衡态转化率基本不变， 但反应速度减小。FTIR检测得气态产物主要由CO 、COS 、CS 、SO 组成，而且XPS 、XRD分析结果 2 2 2 显示硫化产物Ni S 的质量百分含量随循环数增加而减小。SEM表明还原态NiO载氧体颗粒表面呈现烧 3 2 结现象。 关键词：化学链燃烧；NiO 载氧体硫化；CO2 分离；反应机理; 表面烧结 Mechanism of Hydrogen Sulfide reaction with Ni-based Oxygen Carrier in Chemical Looping Combustion GAO Zheng-ping, SHEN Lai-hong, XIAO Jun, WU Jia-hua (Thermoenergy Engineering Research Institute, Southeast University, Nanjing, 210096, China) Abstract ：Chemical looping combustion (CLC) is an indirect combustion technology with inherent separation of the greenhouse gas CO2 . The reactivity of NiO oxygen carrier reaction with highly concentration mixed gas of carbon monoxide and hydrogen sulfide has been investigated by means of thermogravimetric analyzer and Fourier Transform Infrared spectrum analyzer at 900 ºC. The experiment results indicates that the conversion ratio of NiO oxygen carrier is nearly same at equilibrium state as cycle number increases, however, the reaction speed decreases gradually. Furthermore, the gaseous production in exhaust are consisted of CO 、COS、CS and SO . With the increase of cyclic reduction number, the experimental result 2 2 2 demonstrates that the content of Ni S in the reduced