整体式Mn基低温脱硝催化剂研究.pdfVIP

学兔兔 化 工 进 展 2015年第34卷增刊1 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ．127． 0 0口 0 0 i研究开发l 身 ‘ ， 整体式Mn基低温脱硝催化剂研究 王学海 ，吴吴 ，刘忠生 ( 抚顺石油化工研究院，辽宁抚顺113001；。辽宁石油化工大学，辽宁抚顺 113001) 摘要：采样硝酸锰和乙酸锰两种Mn的前体制备以堇青石为基体的整体式脱硝催化剂，并进行了氨选择性催化 还原N0反应 (NH3一SCR)和BET、XRD、XPS等表征。以硝酸锰为前体的催化剂具有更好的低温脱硝活性， 在反应温度15O～250℃的范围内，MnN／TiO2／cc催化剂的脱硝率接近100 ；而当反应温度超过250℃后， MnA／Ti02／cc催化剂比MnN／TiOz／cc催化剂具有更高的脱硝活性。表面Mn活性位和弱酸位多是MnN／ Ti02／cc催化剂低温SCR活性好的主要原因。 关键词：低温；脱硝；堇青石蜂窝陶瓷基体；锰 Performance of monolithic Mn catalyst for low temperature SCR WANG Xuehai ，WU Hao ，LIU Zhongsheng ( Fushun Research Institute of Petroleum and Petrochemicals，SINOPEC，Fushun 113001，Liaoning，China； 。Liaoning Shihua University，Fushun 113001，Liaoning，China) Abstract：Monolithic Mn catalysts were prepared by two different Mn precursors(manganese nitrate and manganese acetate)，and these catalysts were characterized by BET，)a ，Ⅺ)S and NH3一SCR The catalyst prepared by manganese nitrate has higher low-temperature de NOz activity than that prepared by manganese acetate．The de NO efficiency of MnN／TiO2／02 catalyst was close to 100 in the reaction temperature between 150℃ and 250℃．However。when the reaction temperature was above 250℃，the activity of MnA／TiO2／02 catalyst was better than MnN／TiO2／02 catalyst．Characterization results showed that higher surface Mn concentration and weak acids were found on ／TiO2／02 catalyst． Key words：low temperature；deNO ；cordierite ceramic honeycomb；manganese 来自固定源 (电厂、工业锅炉及炼厂)的氮氧 塞和中毒的问题。低温SCR工艺 (200℃以下)则 化物 (下称NO ，主要是N0和No )是大气主 避免了上述问题，目前文献报道的低温脱硝催化剂 要污染物，它导致酸雨和光化学烟雾的形成，并对