酯复配内给电子体催化剂的制备及其乙烯聚合评价.pdfVIP

学兔兔 化 工 进 展 2010年第29卷第9期 CHEMICAL INDUSTI Y AND ENGINEER G PR0GReSS ·1645· 酮／酯复配内给电子体催化剂的制备及其乙烯聚合评价 王卫锋 ，张瑞 ～，白鹏 ，杨敏 ，郝月梅 ，圈 ，刘宾元 ( 河北工业大学化工学院高分子科学与工程研究所，天津 300130； 中国石油大庆化工研究中心，黑龙江 大庆 163714) 摘 要：用酮类和二酯类为复配内给电子体制备了一种高效乙烯聚合催化剂，用FrlR分析了单个内给电子和复 配内给电子体对催化剂结构的影响，结果表明3种催化剂中给电子性能为邻苯二甲酸邻苯二甲Ca=-异丁酯乙酰 丙酮二异丁酯乙酰丙酮。用凝胶渗透色谱 (GPC)和差示扫描量热仪 (DSC)对3种催化剂所制备的聚乙烯进 行了表征，与单个内给电子体催化剂制备的聚乙烯相比，复配内给电子体催化剂所制备的聚乙烯具有更高的聚 合活性，更明显的 “共单体效应”和更宽的相对分子量分布。 关键词：复配；内给电子体；共单体效应；分子量分布；聚乙烯 中图分类号：TQ 221．21 文献标志码：A 文章编号：1000—6613(2010)09—1645—04 Internal electron donor by ketone／ester compound in catalysts for ethylene polymerization WANG ng ，ZHANG Rui“ ，BAIPeng ，YANG Min ，HAO Yuemei ， IYAN Weidong[ ，L，UBinyuan ( Institute of Polymer Science and Engineering，School of Chemical EngineeringTechnology，Hebei University of Technology，Tianjin 300130，China； Daqing Chemical Engineering Research Center，Institute of Pe~ochemical Engineering，PetroChina，Daqing 163714，Heilon由iang，China) Abstract：An efficient ethylene polymerization Zieglar-Natta(Z-N)catalyst was prepared，in which ketone and／or ester was used as internal electron donor compound．The influence of internal electron donor on catalytic performance was analyzed by means of FTIR，which indicated that the elec仃on donating ability is in the order of DIBP(DIBP／ACAC)ACAC．Polyethylenes obtained with these three catalysts were characterized by means of DSC and GPC．The Z—N catalyst bearing internal electron donors composed of ketone and ester component demonstrated hi