催化裂化多产丙烯.pdfVIP

学兔兔 化 工 进 展 2015年第34卷第6期 CHEMICAL INDUSTRY AND ENGINEERING PR0GRESS ·1619· 催化裂化多产丙烯 王梦瑶，周嘉文，任天华，孟祥海，张睿，刘海燕 (中国石油大学(北京)重质油国家重点实验室，北京 102249) 摘要：丙烯作为重要的基本有机化工原料，其市场需求快速增长，除蒸汽裂解工艺外，流化催化裂化 (FCC)是 丙烯生产的另一重要来源。本文主要综述了国内外开发并应用的一系列催化裂化多产丙烯的工艺技术，着重介 绍了各生产工艺技术的特点、产品分布及其工业应用情况，并从催化剂、操作条件和反应器三个方面对催化裂 化多产丙烯的影响因素进行了分析。FCC多产丙烯工艺与常规FCC工艺相比较表明，丙烯收率均有较明显的提 高，并指出通过FCC工艺技术改造增产丙烯已是重要技术路线。 关键词：催化裂化；丙烯；影响因素；优化设计 中图分类号：TE 624．4 文献标志码：A 文章编号：1000—6613(2015)06—1619—06 DoI：10．16085~．issn．1000—6613．2015．06．019 Catalytic cracking processes for maximizing propylene production WANG Mengyao，ZHOUJiawen，PEN Tianhua，MENGXianghai，ZHANGRui，LIUHaiyan (State Key Laboratory ofHeavy Oil Processing，China University ofPetroleum，Beijing 102249，China) Abstract：Propylene is one of the major raw materials used in basic organic chemical industry，and its market demand increases rapidly．In addition to steam cracking，fluid catalytic cracking(FCC)is another important way to produce propylene．This paper mainly discusses a series of catalytic cracking processes for propylene production in both academia and industry．This paper introduces the characteristics，product distribution and industrial applications of these processes in detail，and also analyzes influencing factors for maximizing propylene production in terms of catalysts，operating conditions and reactors．The results showed that the propylene yield of modified technologies increased significantly compared with conventional FCC process．Meanwhile，the technical modification of FCC is an important route for most propylene production． Key words