Al2O3-ZrO2复合氧化物对Cu基催化剂选择加氢性能的影响.pdfVIP

学兔兔 化 工 进 展 ·1898· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2010年第29卷第l0期 Al2O3．ZrO2复合氧化物对Cu基催化剂选择加氢性能的影响 李 锋 ，宋 华 ，李瑞峰 ，唐 龙 ，汪淑影 ( 东北石油大学化学化工学院，黑龙江 大庆 163318； 大庆化工研究中心，黑龙江 大庆 163714) 摘 要：采用共沉淀法制备A12O3．ZrO2复合氧化物，并以此为载体制备负载型cu基催化剂，运用x射线衍射、 x射线能谱、扫描电子显微镜对载体和催化剂进行表征。以糠醛气相加氢制糠醇反应为探针，考察复合氧化物对 cu基催化剂选择加氢活性的影响。结果表明，A12O3一ZrO2复合氧化物中ZrO2的存在会减少CuO与A12O3的接触， 降低Cu基催化剂的深加氢能力；A12O3有助于延迟ZrO2的晶化，避免活性组分Cu嵌入到ZrO2晶格中导致催化 活性下降。载体中ZrO2质量分数为20％时，Cu／A12O3。ZrO2催化剂选择加氢活性最高，与Cu／AI2O3催化剂相比， 该催化剂具有较好的低温加氢活性和高温加氢选择性。 关键词：AI2O3一ZrO2；复合氧化物；Cu基催化剂；选择加氢；糠醛 中图分类号：O 643．36 文献标志码：A 文章编号：1000～6613(2010)lO一1898—05 Effect of A1203一ZrO2 composite oxide on the performance of Cu-based catalyst for selective hydr0genati0n L1Feng ，SONGHua ，LIRuifeng ，TANGLong ，WANGShuying (1Conege ofChemistry and Chemical Engineering，Northeast Petroleum University，Daqing 163318，Heilongjiang， China： Daqing Chemical Engineering Research Center，Daqing 163714，Heilongjiang，China) Abstract：A1203一ZrO2 composite oxides were prepared by coprecipitation and used as supports for Cu—based catalysts prepared by impregnation．The supports and the catalysts were characterized by X—ray diffraction(XRD)，X—ray photoelectron spectroscopy(XPS)，and scanning electron microscopy (SEM)．Effect of the composite oxides on the Cu—based catalysts for selective hydrogenation was studied using vapour phase hydrogenation of fuffural to furfural alcohol as a probe reaction．Results showed that ZrO2 Can reduce the contact between CuO and A1203，and therefore，decrease the deep hydrogenation capacity of the Cu-based catalysts，A1203 can del