BA-HEMA互穿网络型聚合物的合成及性能.pdfVIP

学兔兔 化 工 进 展 2009年第28卷第9期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS PU／BA．HEMA互穿网络型聚合物的合成及性能 张静丽，吴冬梅，张勤勤，杨冬亚，邱凤仙 (江苏大学化学化工学院，江苏 镇江 212013) 摘 要：以异佛尔酮二异氰酸酯(IPDI)、二羟甲基丙酸(DMPA)为硬段，聚醚多元醇(N220)为软段，以丙烯 酸丁酯(BA)和甲基丙烯酸羟乙酯(HEMA)改性，制备了水性聚氨酯 (Pu)分散液，测定了水分散液及其膜 的物理性能和力学性能。结果表明，与未改性的PU水分散液相比，改性聚氨酯水分散液的粒径均有所增大，表 面张力减小，力学性能和硬度提高。HEMA的引入，形成了具有化学交联的核一壳互穿网络结构的聚合物，说明 改性材料中分子链硬段与PA分子链具有较高的相容性。 关键词：7KI}生聚氨酯；丙烯酸树脂；核壳；乳液 中图分类号：TQ 630．7 文献标识码：A 文章编号：1000—6613(2009)09—1609—04 Preparation and properties of interpenetrating polymer networks from PU／BA．HEMA ZHANG Jingli， Dongmei，ZHANG Qinqin，YANG Dongya，0IUFengxian (School ofChemistry andChemicalEngineering，JiangsuUniversity，Zhenjiang 212013，Jiangsu，China) Abstract：Waterborne polyurethane(PU)aqueous dispersions were prepared by the modification with butyl acrylate(BA)and 2-hydroxyethyl methacrylate(HEMA)，in which the PU was synthesized from isophorone diisocyanate(IPDI)with dihydroxymethylpropionic acid(DMPA)as the hard segment and polyether polyols(N220)as the soft segment．The physical and mechanical properties of the prepared aqueous dispersions and membranes were investigated．Results showed that the modified PU has a larger particle size，a smaller surface tension and improved mechanical properties and hardness as compared with the unmodified PU．The introduction of HEMA resulted in the formation of a chemical crosslinked core-shell interpenetrating polymer network structure，indicating that the hard segment of PU has a higher molecular chain compatibility with the acrylic polymers in the modified materials． Key words：waterborne polyurethane；acry