Eu（3＋）掺杂TiO_2荧光探针的制备及对氯氰菊酯的检测应用.pdfVIP

学兔兔 化 工 进 展 2012年第3 1卷第2期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·417· Eu3+掺杂TiO2荧光探针的制备及对氯氰菊酯的检测应用 姚 飞，谭春雷，王文霞，张小娟，卢 荣 (西北大学化工学院，陕西 西安 710069) 摘 要：以钛酸四丁酯为前体，采用液相法制备了水溶态纳米Eu 掺杂TiO，荧光探针，并对其发光性质进行了 研究。通过紫外吸收和荧光光谱研究了它和氯氰菊酯之间的相互作用，结果发现，氯氰菊酯对 Eu¨掺杂 TiO， 的荧光具有猝灭作用，根据 Stem—Volmer猝灭方程，计算出其猝灭常数为1．017×10“L／(mol·S1，并讨论了猝灭 机理。依据氯氰菊酯浓度和Eu 掺杂TiO2的荧光强度成正比，建立了一种快速检测农药的新方法。其检测范围 为2．5x10 ～2．5x10_。mol／L，检出限为2．5x10_。 mol／L，回收率在89．25％～93．55％之间。 关键词：二氧化钛；荧光光谱；氯氰菊酯；荧光猝灭 中图分类号：0 614．33 文献标志码：A 文章编号：1000—6613(2012)02—0417—04 Preparation of Eu针doped with TiO2 fluorescent probe and its application on the detection of cypermethrin YAO Fei， ⅣChunlei，WANG Wenxia，ZHANGXiaojuan，LURong (College ofChemical Engineering，Northwestem University，Xi’an710069，Shaanxi，China) Abstract：Using tetrabutyl titanate as a precursor，the nanometer Eu doped TiO2 was prepared by sol-gel method，and the property of luminescence of nano—powder was studied．The interaction of cypermethrin with Eu”一TiO2 was studied by absorption and fluorescence spectroscopy~The results indicated that the fluorescence intensity of Eu3+_TiO2 was quenched by cypermethrin and the quenching rate constant(kq)was 1．OlTx10“L／(mol‘S1 according to the Stern—Volmer equation，and the mechanism of quench had been discussed．A new rapid method for detection of pesticides was established according to that the fluorescence intensity of Eu3+-TiO2 was proportional to cypermethrin concentration．The range ofdetection was 2．5x10一 一2．5xlO mol／L，the detection limit(3a)was 2．5x10一n mol／L and the recovery was 89． 25％一93．55％．