Et_3NHCl恒电流法电沉积铝.pdfVIP

学兔兔 化 工 进 展 2011年第30卷第10期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·2151· 磁力搅拌下离子液体AICI3／Et3NHCI恒电流法电沉积铝 狄超群，张鹏远，徐联宾，陈建峰 (北京化工大学超重力工程研究中心，北京 100029) 摘 要：磁力搅拌下，在 1．75A1C13／Et3NHC1离子液体中不锈钢电极片上利用恒电流法电沉积制备金属铝。研究 发现，A1C13／E 3NHC1离子液体的黏度随温度的升高而减小，l 与r 符合线性关系；A1C1 ／Et3NHC1离子液体 的电导率随温度的升高而增大，符合Arrhenius公式。磁力搅拌下恒电流法电沉积铝实验结果表明，转速低于700 r／rnin时电流效率和沉积速率随着转速的增大而升高，沉积物表面形貌逐渐平整致密，颗粒细化。温度70℃、 电流密度22 mA／clTI 、转速700 r／min、电沉积90 rain下，沉积铝的表面形貌相对比较平整致密，电流效率达到 78％，沉积铝的纯度 (质量分数)达到97％。 关键词：离子液体A1C13／Et3NHC1；恒电流电沉积法；磁力搅拌；铝；电流效率；沉积速率 中图分类号：O 646．5 文献标志码：A 文章编号：1000—6613(2011)10—2151—08 Constant current electr0depOsiti0n of aluminum from AICI3／Et3NHCI ionic liquid under magnetic stirring DI Chaoqun，ZHANG Pengyuan，XULianbin，CHENJianfeng (Research Center of the Ministry of Education for High Gravity Engineering and Technology， Beijing University of Chemical Technology，Beijing 100029，China) Abstract：Aluminum was successfully electrOdeDosited on stainless stee1 electrodes from aluminum chloride(A1C13)／triethylamine hydrochloride(Et3NHC1)ionic liquids by constant current electrolysis under magnetic stirring conditions．The electrical conductivities of ionic liquids increased as the electrolyte temperature increased，agreeing with Arrhenius equation．The viscosities of ionic liquids decreased as the electrolyte temperature increased，with a linear relationship of lnp and T- 。The constant current deposition experiments showed that when the stirring speed wa