H6P2W18o62／C催化合成环己烯.pdfVIP

学兔兔 化 工 进 展 2014年第33卷第3期 CHEMICAL INDUSTRYAND ENGINEERING PROGRESS ·685· H6P2W18o62／C催化合成环己烯 曹小华 ，王原平 ，徐常龙 ，占昌朝 ，雷艳虹 ( 九江学院化学与环境工程学院，江西 九江332005； 九江职业大学，江西 九江 332000) 摘要：以活性炭为载体，用浸渍法制备出负载型Dawson结构磷钨酸(H6P2WI8O62／C)催化剂，通过FI-IR和SEM 对催化剂进行表征，以环己醇脱水合成环己烯为探针反应，考察催化剂的酸催化性能。实验结果表明， H6P2W1 8062／C表现出良好的催化活性。在优化反应条件下：W(H6P2W18O62／C)=6．2％(基于环己醇质量)，反应 温度为180℃，反应时间为40rain，环己烯收率可达89．1％，催化剂重复使用5次后，收率仍可达80-3％。 关键词：Dawson结构磷钨酸；活性碳；催化；合成 中图分类号：TQ 426．6 文献标志码：A 文章编号：1000～6613(2014)03—0685—04 DoI：l0．3969~．issn．1000—6613．2014．03．028 Dehydration of cyclohexanol to cyclohexene over H6P2W18062／C Catalyst CA0Xiaohua 2 WANG Yuanping ，XUChanglong ，ZHANChangchao ，LEIYanhong ， ( College ofChemistry and Environmental Engineering，Jiujiang University，Jiujiang 332005，Jiangxi，China： Jiujiang Vocational University，Ji@ang 332000，Jiangxi，China) Abstract：Dawson—type phosphotungstic acid(H6P2WI8062)supported on activated carbon (H6P2W1 8O62／C)solid acid catalyst was prepared by impregnation method and characterized by FT_IR and SEM．The catalytic performance was studied in the catalytic synthesis of cyclohexene from cyclohexano1．It was found that H6P2W1 8062／C had good catalytic properties for the dehydration of cyclohexanol to cyclohexene．Under the optimal condition，f ． e．W(catalyst)=6．2％(relative to the dosage of cyclohexano1)，reaction temperature of 180℃ and reaction time of 40 min．the yield of cyclohexene reached 89．I％．The activity ofH6P2W18062／C catalyst remained basically unchanged after five rLlns