HTS-1钛硅分子筛催化环己酮氨肟化工业试验.pdfVIP

学兔兔 化 工 进 展 2010年第29卷第1期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·187· HTS．1钛硅分子筛催化环己酮氨肟化工业试验 顾耀明1,2刘春平 ，程立泉 一，朱泽华 ( 南京工业大学材料化学工程国家重点实验室，江苏 南京 210009； 中国石化巴陵分公司，湖南 岳阳414007 中国石化石油化工科学研究院，北京 100083) 摘 要：通过工业试验，考察了钛硅分子筛HTS．1新剂和再生剂在环己酮氨肟化制备环己酮肟工艺中的工业试验 性能，S-,_lk运行结果显示：环己酮转化率99．6％，环己酮肟选择tt~99．5％，催化剂单程寿命大于600 h。同时介 绍了亚微米级HTS一1催化过程中的分离和粘壁问题及其．Y-程解决措施，应用陶瓷膜微滤技术解决了催化剂和反应 液的分离和循环使用问题，应用波纹管技术克服了催化剂粘壁现象，达到正常换热的效果，并通过优化使系统满 足生产要求。 关键词：环己酮肟；钛硅分子筛HTS．1；氨肟化：_Y-业试验；膜分离 中图分类号：TQ 032．4；TQ 236 文献标识码：A 文章编号：1000—6613(2010)01—0187—05 Industrial research on cyclOhexanOne-oxime synthesis catalyzed with HTS．1 molecular sieves GUYaoming ’。，LIU ch．npi．g，CHENG Liquan ，ZHUZehua3 ( State Key Laboratory ofMaterials Oriented Chemical Engineering，Nanjing University ofTechnology， Nanjing 210009，Jiangsu，China； SINOPEC Baling Company，Yueyang 414007,Hunan，China； SINOPEC Research Institute ofPetroleum Processing，Beijing 100083，China) Abstract：Through industrial trials for cyclohexanone—oxime synthesis catalyzed with molecular sieves HTS．1，the activity and the life of flesh and regenerated HTS．1 catalysts have been investigated．The running results showed that the conversion of cyclohexanone was above 99．6％，and the selectivity for cyclohexanone oxime was above 99．5％，and the single circle life of HTS一1 was no less than 600 h．The separation and on—line recycle of HTS—l catalyst were achived through ceramic microfiltration，and the wall—sticking problem of HTS-1 catalyst was resolved through a technology of