SEBS共混物的相形态、光学及力学性能.pdfVIP

学兔兔 化 工 进 展 2010年第29卷第7期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·1281· PP／SEBS共混物的相形态、光学及力学性能 张德强，丁雪佳，褚文娟，袁 园，韩海军，张丽娟 (北京化工大学，北京市新型高分子材料制备与加工重点实验室，北京 100029) 摘 要：将聚丙烯 (PP)与氢化聚苯乙烯一丁二烯一聚苯乙烯嵌段共聚物 (SEBS)在双螺杆挤出机中熔融共混，制 备得到透明PP／SEBS共混物，并利用透光率雾度测定仪、广角x射线衍射仪、偏光显微镜、ARES流变扩展系 统等进行表征。结果表明，随着SEBS含量的提高，聚丙烯的结晶性下降，共混物的透明性和低温冲击强度明显 提高，而拉伸强度随之降低。流变学研究表明，随着SEBS含量的增加，PP／SEBS共混物形态由海岛结构逐渐演 变为双连续相结构。 关键词：聚丙烯；氢化聚苯乙烯一丁二烯一聚苯乙烯嵌段共聚物；透明；结晶 中图分类号：TQ 325．14；TQ 334．3 文献标识码：A 文章编号：1000—6613(2010)07—1281—05 Phase behavior，optical and mechanical properties of PP／SEBS binary blend ZHANG Deqiang，DING Xuejia，CHU WenjRan，YUAN Yuan，HANHaijun，ZHANG LUuan (The Key Laboratory of Preparation and Processing of Novel Polymer of Beijing City，Beijing University of Chemical Technology，Beijing 100029，China) Abstract：The blends of polypropylene(PP)and styrene—ethylene／butylene—styrene elastomer(SEBS) were prepared by melt blending with a twin screw extruder．The phase behavior of the blends was investigated by means of wide angle X—ray diffraction，optical microscopy and a rheometer． Crystallizability of the blends was decreased as the increase in SEBS content，for which the haze values of injection-molded plaques decreased．The PP／SEBS blends showed a decreased tensile s~ength and and a increased impact s~ength as compared with PE Results of rheological study showed that the blends turned to be CO—continuous phase behavior as the increase in SEBS content． Key words：polypropylene；styrene—ethylene／butylene—styrene elastomer；transparent；crystallization 聚丙烯(PP)以其优异的力学性能、价格低廉、